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How many of the following compounds will...

How many of the following compounds will form acetic acid on reaction with acidic `KMnO_(4)` ?
Prop-1- ene, 2-Methylbut-2-ene, 2- Methylpropene,But-2-ene, Cyclohexene.

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To determine how many of the given compounds will form acetic acid upon reaction with acidic KMnO4, we need to analyze each compound based on the oxidation reaction with KMnO4, a strong oxidizing agent. ### Step-by-Step Solution: 1. **Identify the Compounds**: - Prop-1-ene: CH3-CH=CH2 - 2-Methylbut-2-ene: CH3-C(CH3)=CH2 - 2-Methylpropene: CH3-C(CH3)=CH2 - But-2-ene: CH3-CH=CH-CH3 - Cyclohexene: C6H10 (a cyclic alkene) 2. **Understand the Reaction with KMnO4**: - KMnO4 cleaves the double bond in alkenes and converts the carbon atoms involved in the double bond to carboxylic acids (COOH) if they contain hydrogen atoms. - If one of the carbons in the double bond does not have a hydrogen atom, it will be converted to a ketone instead. 3. **Analyze Each Compound**: - **Prop-1-ene (CH3-CH=CH2)**: - The double bond is between CH3 and CH2. The carbon in CH2 has a hydrogen. Thus, it will form acetic acid (CH3COOH) and formic acid (HCOOH), which decomposes to CO2. - **2-Methylbut-2-ene (CH3-C(CH3)=CH2)**: - The double bond is between the carbon with CH3 and CH2. The CH2 has a hydrogen, leading to the formation of acetic acid (CH3COOH) from one side and a ketone from the other side. - **2-Methylpropene (CH3-C(CH3)=CH2)**: - Similar to the previous compound, the double bond involves a carbon with a hydrogen (CH2), leading to the formation of acetic acid (CH3COOH) and a ketone from the other side. - **But-2-ene (CH3-CH=CH-CH3)**: - The double bond is between two carbons that both have hydrogen atoms. This will also lead to the formation of acetic acid (CH3COOH) from both sides. - **Cyclohexene (C6H10)**: - The double bond is between two carbons in a cyclic structure, both of which have hydrogen atoms. This will also lead to the formation of carboxylic acids from both sides. 4. **Count the Compounds that Form Acetic Acid**: - **Prop-1-ene**: Forms acetic acid. - **2-Methylbut-2-ene**: Forms acetic acid. - **2-Methylpropene**: Forms acetic acid. - **But-2-ene**: Forms acetic acid. - **Cyclohexene**: Forms acetic acid. ### Conclusion: All five compounds will form acetic acid upon reaction with acidic KMnO4. **Final Answer**: 5 compounds will form acetic acid.
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Which of the following compounds shows geometrical isomerism (G.I.) ? a. But -2- ene b. 3- Methyl but -2- enoic acid c. 3- Methyl pent -2- enoic acid d. 3- Phenyl prop -2- enoic acid.

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Knowledge Check

  • 2-methylbut-2-ene will be represented as

    A
    `CH_3 - underset(CH_3) underset(| ) (CH ) - CH_2 - CH_3`
    B
    `CH_3 - underset(CH_3) underset(| ) C =CH -CH_3`
    C
    `CH_3 - CH_2 - overset(CH_3)overset(|)(C ) - CH_2`
    D
    `CH_3 - underset(CH_3) underset(|) (CH ) - CH = CH_2`
  • Classify the following compounds as primary, secondary and tertiary halides. (i) 1-bromobut-2-ene (ii). 4-Bromopent-2-ene (iii). 2-Bromo-2-methylpropane

    A
    (i)-secondary,(ii)-tertiary,(iii)-primary
    B
    (i)-secondary,(ii)-primary,(iii)-tertiary
    C
    (i)-primary,(ii)-tertiary,(iii)-secondary
    D
    (i)-primary,(ii)-secondary,(iii)-tertiary
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