Phenol is

A

A base weaker than ammonia

B

An acid stronger than carbonic acid

C

An acid weaker that carbonic acid

D

A neutral compound

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct characterization of phenol from the given options, let's analyze each option step by step. ### Step 1: Understanding the Structure of Phenol Phenol has the molecular formula C6H5OH. It consists of a hydroxyl group (-OH) attached to a benzene ring. This structure is crucial for understanding its acidic and basic properties. **Hint:** Remember that the presence of the hydroxyl group in phenol is key to its acidic behavior. ### Step 2: Analyzing Option A - "A base weaker than ammonia" Ammonia (NH3) is a well-known base due to its ability to donate a lone pair of electrons. In phenol, the lone pair of electrons on the oxygen atom is involved in resonance with the aromatic ring, making it less available for donation. Therefore, phenol is indeed a weaker base than ammonia. **Hint:** Compare the availability of lone pairs in both compounds to assess their basicity. ### Step 3: Analyzing Option B - "An acid stronger than carbonic acid" To evaluate this, we need to compare the acidity of phenol with carbonic acid (H2CO3). When phenol donates a proton, it forms the phenoxide ion (C6H5O-), which has several resonance structures that stabilize the negative charge. In contrast, carbonic acid, when it loses a proton, forms bicarbonate (HCO3-), which has fewer resonance structures. The stability of the conjugate base (phenoxide ion) indicates that phenol is a weaker acid than carbonic acid. **Hint:** Consider the stability of the conjugate bases formed after deprotonation to determine acidity. ### Step 4: Analyzing Option C - "An acid weaker than carbonic acid" From the previous analysis, we established that phenol is indeed a weaker acid than carbonic acid. Therefore, this statement is correct. **Hint:** Look for the number of resonance structures in the conjugate bases to compare acidity. ### Step 5: Analyzing Option D - "A neutral compound" Phenol is not neutral; it can act as an acid by donating a proton. Therefore, this statement is incorrect. **Hint:** Recall that the ability to donate protons indicates that a compound is not neutral. ### Conclusion Based on the analysis: - Option A is correct: Phenol is a weaker base than ammonia. - Option C is correct: Phenol is an acid weaker than carbonic acid. - Options B and D are incorrect. Thus, the correct answers are A and C. ### Final Answer Phenol is: - A. A base weaker than ammonia. - C. An acid weaker than carbonic acid.
Doubtnut Promotions Banner Mobile Dark
|

Similar Questions

Explore conceptually related problems

The ionization constant of phenol is 1.0xx10^(-10) . What is the concentration of phenolate ion in 0.05 M solution of phenol? What will be its degree of ionization if the solution is also 0.01 M in sodium phenolate?

All the Phenols are

Conversion of Phenol into aniline

Conversion of Phenol into salicylic acid

Conversion of Phenol to acetophenone

Phenols does not react with

Conversion of Phenol into Toluene .

Conversion of Phenol into benzoic acid

Phenol gives characteristic colouration with

What is the n - factor for the phenol in the following reaction? "phenol"overset((NH_(4))_(2)Cr_(2)O_(7))rarr ?