Home
Class 12
CHEMISTRY
Aldehyde with NH(2)NH(2) forms...

Aldehyde with `NH_(2)NH_(2)` forms

A

Hydrazone

B

Aniline

C

Nitrobenzene

D

none of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of an aldehyde with hydrazine (NH2NH2), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants in this reaction are an aldehyde (general formula RCHO) and hydrazine (NH2NH2). 2. **Understand the Reaction**: When an aldehyde reacts with hydrazine, it undergoes a condensation reaction. In this reaction, the carbonyl group (C=O) of the aldehyde reacts with the hydrazine. 3. **Mechanism of Reaction**: - The nitrogen atom in hydrazine has a lone pair of electrons, which can attack the electrophilic carbon atom of the carbonyl group in the aldehyde. - This results in the formation of a tetrahedral intermediate where the oxygen atom of the carbonyl group becomes negatively charged. 4. **Formation of Hydrazone**: - The negatively charged oxygen can then protonate (lose a hydrogen ion) and water (H2O) is eliminated from the intermediate. - The remaining structure forms a double bond between the carbon and the nitrogen, resulting in the formation of a hydrazone (RCH=N-NH2). 5. **Final Product**: The final product of the reaction is a hydrazone, which is characterized by the presence of a C=N bond. ### Conclusion: The reaction of an aldehyde with hydrazine results in the formation of a hydrazone.
Doubtnut Promotions Banner Mobile Dark
|

Similar Questions

Explore conceptually related problems

What happens when : (i) Acetone reacts with NH_(2)-NH_(2) .

Paragraph for problems 9-15 Compound (A) on reaction with NH_(2) NH_(2) + overset(o-)(O)H is:

Knowledge Check

  • Which of the following form Schiff's base with CH_(3)-NH_(2) ?

    A
    `H_(3)C-overset(O)overset(||)(C)-H`
    B
    `H_(5)C_(6)-overset(O)overset(||)(C)-H`
    C
    `CH_(3)-CH_(2)-OH`
    D
    `H-overset(O)overset(||)(C)-OH`
  • Which of the following is formed as a product when m -dinitrobenzene is treated with (NH_(4))_(2)S ?

    A
    B
    C
    D
  • Similar Questions

    Explore conceptually related problems

    N_(2)+3H_(2) to NH_(3)

    N_(2)+3H_(2) to NH_(3)

    The smallest aldehyde and its next homologue are treated with NH_(2)OH to form oxime. Find out the correct answer out of the following.

    Aldehydes and Ketones react with NH_(2)OH to form aldoximes and Ketoximes respectively. Configuration of these can be determined by Beckmann rearragement as that group migrates which is anti w.r.t -OH Which step is Rate determening step ?

    10 ml N_(2) is reacted with 20 ml H_(2) to form NH_(3) . The correct statements is /are

    Which of the following is formed when As_(2)S_(3) is warmed with NH_(4)OH and H_(2)O_(2) ?