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What is obtained when chlorine is passed...

What is obtained when chlorine is passed in boiling touence an dproduct is hydrolysed?

A

o - cresol

B

p - cresol

C

2, 4 - dihydroxytoluene

D

Benzyl alcohol

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to follow a series of steps to understand the reaction that occurs when chlorine is passed through boiling toluene and the resulting product is hydrolyzed. ### Step-by-Step Solution: 1. **Identify the Structure of Toluene**: Toluene is an aromatic compound with the formula C7H8. Its structure consists of a benzene ring (C6H5) with a methyl group (CH3) attached to it. The chemical structure can be represented as: \[ \text{C}_6\text{H}_5\text{CH}_3 \] 2. **Chlorination of Toluene**: When chlorine (Cl2) is passed through boiling toluene, a substitution reaction occurs. One of the hydrogen atoms on the benzene ring is replaced by a chlorine atom. This process is known as electrophilic aromatic substitution. The product formed is benzyl chloride (C6H5CH2Cl), which can be represented as: \[ \text{C}_6\text{H}_5\text{CH}_2\text{Cl} \] 3. **Hydrolysis of Benzyl Chloride**: The next step involves the hydrolysis of benzyl chloride. Hydrolysis refers to the reaction with water, where the chlorine atom is replaced by a hydroxyl group (OH). This can be represented as: \[ \text{C}_6\text{H}_5\text{CH}_2\text{Cl} + \text{H}_2\text{O} \rightarrow \text{C}_6\text{H}_5\text{CH}_2\text{OH} + \text{HCl} \] In this reaction, the Cl atom is replaced by an OH group, resulting in the formation of benzyl alcohol (C6H5CH2OH) and hydrochloric acid (HCl) as a byproduct. 4. **Final Product**: The final product after hydrolysis is benzyl alcohol, which is represented as: \[ \text{C}_6\text{H}_5\text{CH}_2\text{OH} \] ### Conclusion: When chlorine is passed through boiling toluene and the product is hydrolyzed, the final product obtained is benzyl alcohol.
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Knowledge Check

  • Ethyl alcohol is obtained when ethyl chloride is boiled with :

    A
    alcoholic KOH
    B
    aqueous KOH
    C
    water
    D
    aqueous `KMnO_4`
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