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An ideal gas (gamma = 1.5) undergoes a t...

An ideal gas `(gamma = 1.5)` undergoes a thermodynamic process in which the temperature and pressure of the gas are related as `T^(-1)P^(2)`= constant. The molar heat capacity of the gas during the process is

A

`(3)/(2)R`

B

`(4)/(3)R`

C

`(5)/(2)R`

D

`3R`

Text Solution

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The correct Answer is:
To find the molar heat capacity of the ideal gas undergoing the specified thermodynamic process, we can follow these steps: ### Step 1: Understand the relationship between temperature and pressure We are given that \( T^{-1} P^2 = \text{constant} \). Let's denote this constant as \( k \). This can be rearranged to express pressure in terms of temperature: \[ P^2 = k T \] From this, we can express pressure \( P \) as: \[ P = \sqrt{k T} \] ### Step 2: Use the ideal gas law The ideal gas law states: \[ PV = nRT \] Substituting \( P \) from our previous expression into the ideal gas law gives: \[ \sqrt{k T} V = nRT \] ### Step 3: Rearranging the equation Rearranging the equation to isolate \( P \) gives us: \[ P = \frac{nRT}{V} \] Now, since we have \( P^2 \) in terms of \( T \), we can relate \( P \) and \( T \) through the volume \( V \). ### Step 4: Identify the type of process From the relation \( P^2/T = \text{constant} \), we can identify that this is a polytropic process where: \[ PV^x = \text{constant} \] Comparing with the standard form, we find: \[ x = -1 \] ### Step 5: Calculate the molar heat capacity The formula for the molar heat capacity \( C \) during a polytropic process is given by: \[ C = R \left( \frac{1}{\gamma - 1} + \frac{1}{1 - x} \right) \] Substituting \( \gamma = 1.5 \) and \( x = -1 \): \[ C = R \left( \frac{1}{1.5 - 1} + \frac{1}{1 - (-1)} \right) \] Calculating each term: \[ C = R \left( \frac{1}{0.5} + \frac{1}{2} \right) = R \left( 2 + 0.5 \right) = R \left( \frac{5}{2} \right) \] ### Step 6: Final result Thus, the molar heat capacity of the gas during the process is: \[ C = \frac{5R}{2} \]
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