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Does phenol react with NaHCO(3) solution...

Does phenol react with `NaHCO_(3)` solution ?

A

Phenol is a weaker acid than carbonic acid

B

Phenol is stronger acid than carbonic acid

C

Phenol is as strong as carbonic acid

D

Phenol is insoluble in water.

Text Solution

AI Generated Solution

The correct Answer is:
To determine whether phenol reacts with sodium bicarbonate (NaHCO₃) solution, we can analyze the acidity of phenol compared to carbonic acid, which is the acid that sodium bicarbonate can react with. ### Step-by-Step Solution: 1. **Understanding the Reactivity of Acids with NaHCO₃**: - Sodium bicarbonate is a weak base and reacts with acids to produce carbon dioxide (CO₂) gas. - The reaction occurs when the acid is stronger than carbonic acid (H₂CO₃). **Hint**: Remember that only stronger acids than carbonic acid will react with sodium bicarbonate. 2. **Acidity of Phenol**: - Phenol (C₆H₅OH) is known to be acidic, but it is a weak acid compared to stronger acids. - The acidic nature of phenol is due to the presence of the hydroxyl (-OH) group, which can donate a proton (H⁺). **Hint**: Identify the functional group in phenol that contributes to its acidity. 3. **Comparison with Carbonic Acid**: - Carbonic acid (H₂CO₃) is a weak acid that can dissociate to release H⁺ ions. - When comparing the acidity of phenol and carbonic acid, phenol is a weaker acid than carbonic acid. **Hint**: Consider the strength of the acids based on their ability to donate protons. 4. **Conclusion on Reaction**: - Since phenol is a weaker acid than carbonic acid, it will not react with sodium bicarbonate. - Therefore, phenol does not react with NaHCO₃ solution. **Hint**: Recall that the reactivity of an acid with a base depends on their relative strengths. ### Final Answer: Phenol does not react with sodium bicarbonate (NaHCO₃) solution because it is a weaker acid than carbonic acid.
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Knowledge Check

  • Which of the following compounds will react with NaHCO_(3) solution to give sodium salt and carbon dioxide?

    A
    Acetic acid
    B
    n-Hexanol
    C
    Phenol
    D
    both (b) and (c).
  • Which of the following compounds will react with NaHCO_(3) solution to give sodium salt and carbon dioxide?

    A
    Acetic acid
    B
    n-Hexanol
    C
    Phenol
    D
    both (b) and (c).
  • Which of the following compounds will react with NaHCO_(3) solution to give sodium salt and carbon dioxide?

    A
    Acetic acid
    B
    n-Hexanol
    C
    Phenol
    D
    both (b) and (c).
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