Home
Class 12
CHEMISTRY
The compound (C) in the given sequence o...

The compound (C) in the given sequence of reaction is ,
`C_6H_5OHoverset(NaOH)rarr(A)overset(CO_2)rarr(B)overset(HCl)rarr(C)`

A

chlorobenzene

B

Benzoic acid

C

Salicyladehyde

D

Salicylic acid

Text Solution

AI Generated Solution

The correct Answer is:
To determine the compound (C) in the given sequence of reactions, we will analyze each step of the reactions involving phenol (C6H5OH). ### Step-by-Step Solution: 1. **Identify the starting compound:** The starting compound is phenol, which has the molecular formula C6H5OH. 2. **Reaction with Sodium Hydroxide (NaOH):** When phenol reacts with sodium hydroxide, it forms the sodium salt of phenol. This is a deprotonation reaction where the hydroxyl (-OH) group of phenol loses a hydrogen ion (H+) and forms sodium phenoxide (C6H5O^- Na^+). **Reaction:** C6H5OH + NaOH → C6H5O^- Na^+ + H2O **Intermediate (A):** Sodium phenoxide (C6H5O^- Na^+) 3. **Reaction with Carbon Dioxide (CO2):** The sodium phenoxide then reacts with carbon dioxide under specific conditions (high temperature and pressure). This reaction is known as the Kolbe-Schmitt reaction, which results in the formation of sodium salicylate. **Reaction:** C6H5O^- Na^+ + CO2 → C6H4(OH)(COO^- Na^+) (sodium salicylate) **Intermediate (B):** Sodium salicylate (C6H4(OH)(COO^- Na^+)) 4. **Reaction with Hydrochloric Acid (HCl):** Finally, when sodium salicylate is treated with hydrochloric acid, it leads to the formation of salicylic acid by protonating the carboxylate group. **Reaction:** C6H4(OH)(COO^- Na^+) + HCl → C6H4(OH)(COOH) + NaCl **Final Compound (C):** Salicylic acid (C6H4(OH)(COOH)) ### Conclusion: The compound (C) in the given sequence of reactions is **salicylic acid**.
Doubtnut Promotions Banner Mobile Dark
|

Similar Questions

Explore conceptually related problems

In the given reaction sequence C_6H_5-COOHoverset(SOCl_2)rarr(A)overset(NH_2OH)rarr(B)overset(NaOH//Delta)rarr(C), 'C' will be

What is the end product in the following sequence of reactions ? C_6H_5COOH overset(PCl_5)(rarr)Poverset(2NH_3)(rarr)Qoverset("Reduction")(rarr)R

The end product of the reaction, Ethyl amine overset(HNO_(2))rarr(A)overset(PCl_(5))rarr(B)overset(KCN)rarr(C ) (C) is,

Consider the following sequence of reactions : C_6H_5CH_3overset(Cl_2)rarrp-ClC_6H_4CH_3overset(NBS)rarr(X) overset(Mg)rarr(Y)overset((i)"ethylene oxide")rarr(Z) Final product (Z) is

Give the strutures of (A), (B) and (C ) in the following reactions : C_(6)H_(5)NO_(2) overset(Fe //HCI)rarr (A) overset(HNO_(2))underset(273K)rarr (B) overset(C_(6)H_(5)OH)rarr (C)

Let overset(rarr)C = overset(rarr)A+overset(rarr)B then :

Identify the product (E ) in the following sequence of reactions. overset(Br_2)(rarr)Aoverset(Sn//HCl)(rarr)B underset(273-278K)overset(NaNO_2//HCl)(rarr)Coverset(H_2O // H_3PO_2)(rarr) Dunderset(OH^-)overset(KMnO_4)(rarr)E

Consider the following sequence of reactions C_(2)H_(5)C -= CH overset(CH_(3)MgBr)rarr A underset((2)H_(2)O^(+))overset((1)HCHO) rarr B The product (B) is

The product D of the reaction CH_(3)Cl overset( KCN) ( rarr) ( A) overset( H_(2) O) ( rarr) (B) overset( NH_(3))(rarr) ( C ) overset( Delta)( rarr) ( D ) is

The compound (A) in the following reaction sequence is: (A) overset(PCl_(5))(rarr) " (B) " overset("Alc KOH")(rarr) " ( C) " overset(H_(2)// Ni )(rarr) Propane :