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In the reaction, CrO(5)+SnCl(2) to CrO(4...

In the reaction, `CrO_(5)+SnCl_(2) to CrO_(4)^(2-) +SnCl_(4)`,the element undergoing oxidation and reduction respectively, are:

A

Cr, Sn

B

Sn , Cr

C

Sn , O

D

Cl , O

Text Solution

AI Generated Solution

The correct Answer is:
To determine the elements undergoing oxidation and reduction in the reaction \( \text{CrO}_5 + \text{SnCl}_2 \rightarrow \text{CrO}_4^{2-} + \text{SnCl}_4 \), we need to analyze the oxidation states of the elements involved. ### Step-by-Step Solution: 1. **Identify the oxidation states of chromium (Cr) and tin (Sn):** - In \( \text{CrO}_5 \), chromium (Cr) has an oxidation state of +6. This is because oxygen (O) typically has an oxidation state of -2, and there are 5 oxygen atoms contributing a total of -10. To balance this, Cr must be +6. - In \( \text{CrO}_4^{2-} \), chromium (Cr) still has an oxidation state of +6. The overall charge of -2 from the \( \text{CrO}_4^{2-} \) means that Cr must still be +6 to balance the -8 from the four oxygen atoms (-2 each). 2. **Identify the oxidation states of tin (Sn):** - In \( \text{SnCl}_2 \), tin (Sn) has an oxidation state of +2. Each chlorine (Cl) has an oxidation state of -1, and with two Cl atoms, this totals -2, balancing Sn's +2. - In \( \text{SnCl}_4 \), tin (Sn) has an oxidation state of +4. With four Cl atoms at -1 each, the total is -4, balancing Sn's +4. 3. **Determine changes in oxidation states:** - **For chromium (Cr):** The oxidation state remains +6 in both reactants and products, indicating no change. - **For tin (Sn):** The oxidation state changes from +2 in \( \text{SnCl}_2 \) to +4 in \( \text{SnCl}_4 \). This is an increase in oxidation state, indicating that tin is oxidized. - **For oxygen (O):** In \( \text{CrO}_5 \), the oxidation state of oxygen is -1 (as part of a peroxide), and in \( \text{CrO}_4^{2-} \), the oxidation state of oxygen is -2. This is a decrease in oxidation state, indicating that oxygen is reduced. 4. **Conclusion:** - The element undergoing oxidation is tin (Sn), and the element undergoing reduction is oxygen (O). ### Final Answer: - The element undergoing oxidation is **tin (Sn)** and the element undergoing reduction is **oxygen (O)**.
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Knowledge Check

  • Consider the following reactions, (I) SnCl_(2) + 2FeCl_(3) rarr SnCl_(4) + 2FeCl_(2)

    A
    `SnCl_(2)` is oxidised and `FeCl_(3)` acts as oxidising agent.
    B
    `FeCl_(3)` is oxidised and acts as oxidising agent.
    C
    `SnCl_(2)` is reduced and acts as oxidising agent.
    D
    `FeCl_(3)` is oxidised and `SnCl_(2)` acts as a oxidising agent.
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