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In the sequence of reactions C(6)H(5)B...

In the sequence of reactions
`C_(6)H_(5)Broverset(Mg)underset("ether")rarr (X) overset((i)CO_(2))underset((iii)H_(3)O^(+))rarr(Y)` the product (Y) is

A

biphenyl

B

m - bromobenzoic acid

C

benzoic acid

D

benzyl alcohol

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the sequence of reactions step by step. ### Step 1: Identify the starting compound The starting compound is phenyl bromide, which has the formula \( C_6H_5Br \). ### Step 2: Reaction with Magnesium and Ether When phenyl bromide reacts with magnesium in an ether solvent, it forms a Grignard reagent. The reaction can be represented as: \[ C_6H_5Br + Mg \xrightarrow{ether} C_6H_5MgBr \] Here, \( C_6H_5MgBr \) is phenyl magnesium bromide, the Grignard reagent (denoted as \( X \)). ### Step 3: Reaction with Carbon Dioxide Next, the Grignard reagent \( C_6H_5MgBr \) reacts with carbon dioxide (\( CO_2 \)). The nucleophilic carbon in the Grignard reagent attacks the electrophilic carbon in carbon dioxide: \[ C_6H_5MgBr + CO_2 \rightarrow C_6H_5COO^- + MgBr^+ \] This results in the formation of a carboxylate ion \( C_6H_5COO^- \). ### Step 4: Hydrolysis with Acid The carboxylate ion formed in the previous step is then treated with a mineral acid (like \( H_3O^+ \)): \[ C_6H_5COO^- + H_3O^+ \rightarrow C_6H_5COOH + OH^- \] This hydrolysis leads to the formation of benzoic acid (\( C_6H_5COOH \)), which is the final product \( Y \). ### Final Answer Thus, the product \( Y \) is benzoic acid, represented as: \[ Y = C_6H_5COOH \] ---
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