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Among the following, the optically inact...

Among the following, the optically inactive compound is

A

B

C

D

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The correct Answer is:
To determine which of the given compounds is optically inactive, we need to understand the concept of chirality and optical activity. ### Step-by-Step Solution: 1. **Understanding Optical Activity**: - Optical activity refers to the ability of a compound to rotate the plane of polarized light. A compound is said to be optically active if it can rotate polarized light, while it is optically inactive if it does not affect the plane of polarized light. 2. **Chirality**: - A compound is chiral if it has a non-superimposable mirror image. This typically occurs when a carbon atom is bonded to four different groups (asymmetrical). If a compound has a plane of symmetry or is superimposable on its mirror image, it is considered achiral and thus optically inactive. 3. **Analyzing the Compounds**: - **Compound 1**: A quaternary ammonium salt with four different groups attached to the nitrogen atom. This compound is chiral and optically active. - **Compound 2**: A phosphorus compound with three different groups and a lone pair. The lone pair creates asymmetry, making this compound chiral and optically active. - **Compound 3**: A carbon atom bonded to two identical groups and one different group. Since it has a plane of symmetry (the two identical groups), this compound is achiral and optically inactive. - **Compound 4**: A carbon atom bonded to four different groups. This compound is chiral and optically active. 4. **Conclusion**: - Among the compounds analyzed, **Compound 3** is the only optically inactive compound because it has a plane of symmetry and is not chiral. ### Final Answer: The optically inactive compound is **Compound 3**.
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Knowledge Check

  • An optically active compound

    A
    rotates the plane of polarised light
    B
    changes the direction of polarised light
    C
    does not allow plane polarised light to pass through
    D
    none of these.
  • Among the following compounds, the most basic compound is :

    A
    B
    C
    D
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