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Among the following series of transition...

Among the following series of transition metal ions, how many metals ions have `d^(2)` electronic configuration
`Fe^(4+), V^(3+), Sn^(2+), Au^(3+)Ti^(2+), As^(3+), Cr^(3+), Mn^(5+)Co^(3+), Zr^(2+), Cd^(2+), Mo^(4+), La^(2+), Ta^(4+), Co^(6+), Ni^(4+)`

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To determine how many transition metal ions from the given list have a `d^(2)` electronic configuration, we will analyze each ion step by step. ### Step-by-Step Solution: 1. **Fe^(4+)**: - Atomic number of Fe = 26. - Electronic configuration of Fe: [Ar] 4s² 3d⁶. - For Fe^(4+), remove 4 electrons (first from 4s, then from 3d): - Configuration: [Ar] 4s⁰ 3d⁴ (not d²). 2. **V^(3+)**: - Atomic number of V = 23. - Electronic configuration of V: [Ar] 4s² 3d³. - For V^(3+), remove 3 electrons: - Configuration: [Ar] 4s⁰ 3d² (this is d²). 3. **Sn^(2+)**: - Atomic number of Sn = 50. - Electronic configuration of Sn: [Kr] 5s² 4d¹⁰ 5p². - For Sn^(2+), remove 2 electrons: - Configuration: [Kr] 5s⁰ 4d¹⁰ 5p² (not d²). 4. **Au^(3+)**: - Atomic number of Au = 79. - Electronic configuration of Au: [Xe] 4f¹⁴ 5d¹⁰ 6s¹. - For Au^(3+), remove 3 electrons: - Configuration: [Xe] 4f¹⁴ 5d⁸ 6s⁰ (not d²). 5. **Ti^(2+)**: - Atomic number of Ti = 22. - Electronic configuration of Ti: [Ar] 4s² 3d². - For Ti^(2+), remove 2 electrons: - Configuration: [Ar] 4s⁰ 3d² (this is d²). 6. **As^(3+)**: - Atomic number of As = 33. - Electronic configuration of As: [Ar] 4s² 3d¹⁰ 4p³. - For As^(3+), remove 3 electrons: - Configuration: [Ar] 4s² 3d¹⁰ 4p⁰ (not d²). 7. **Cr^(3+)**: - Atomic number of Cr = 24. - Electronic configuration of Cr: [Ar] 4s¹ 3d⁵. - For Cr^(3+), remove 3 electrons: - Configuration: [Ar] 4s⁰ 3d³ (not d²). 8. **Mn^(5+)**: - Atomic number of Mn = 25. - Electronic configuration of Mn: [Ar] 4s² 3d⁵. - For Mn^(5+), remove 5 electrons: - Configuration: [Ar] 4s⁰ 3d² (this is d²). 9. **Co^(3+)**: - Atomic number of Co = 27. - Electronic configuration of Co: [Ar] 4s² 3d⁷. - For Co^(3+), remove 3 electrons: - Configuration: [Ar] 4s⁰ 3d⁶ (not d²). 10. **Zr^(2+)**: - Atomic number of Zr = 40. - Electronic configuration of Zr: [Kr] 5s² 4d². - For Zr^(2+), remove 2 electrons: - Configuration: [Kr] 5s⁰ 4d² (this is d²). 11. **Cd^(2+)**: - Atomic number of Cd = 48. - Electronic configuration of Cd: [Kr] 5s² 4d¹⁰. - For Cd^(2+), remove 2 electrons: - Configuration: [Kr] 5s⁰ 4d¹⁰ (not d²). 12. **Mo^(4+)**: - Atomic number of Mo = 42. - Electronic configuration of Mo: [Kr] 5s¹ 4d⁵. - For Mo^(4+), remove 4 electrons: - Configuration: [Kr] 5s⁰ 4d² (this is d²). 13. **La^(2+)**: - Atomic number of La = 57. - Electronic configuration of La: [Xe] 6s² 5d¹. - For La^(2+), remove 2 electrons: - Configuration: [Xe] 6s⁰ 5d¹ (not d²). 14. **Ta^(4+)**: - Atomic number of Ta = 73. - Electronic configuration of Ta: [Xe] 4f¹⁴ 5d³ 6s². - For Ta^(4+), remove 4 electrons: - Configuration: [Xe] 4f¹⁴ 5d² 6s⁰ (this is d²). 15. **Co^(6+)**: - Atomic number of Co = 27. - Electronic configuration of Co: [Ar] 4s² 3d⁷. - For Co^(6+), remove 6 electrons: - Configuration: [Ar] 4s⁰ 3d¹ (not d²). 16. **Ni^(4+)**: - Atomic number of Ni = 28. - Electronic configuration of Ni: [Ar] 4s² 3d⁸. - For Ni^(4+), remove 4 electrons: - Configuration: [Ar] 4s⁰ 3d⁶ (not d²). ### Summary of Results: The ions with `d²` electronic configuration are: - V^(3+) - Ti^(2+) - Mn^(5+) - Zr^(2+) - Mo^(4+) - Ta^(4+) Thus, the total number of transition metal ions with a `d²` electronic configuration is **6**.
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Knowledge Check

  • Which of the following pairs of ions have the same electronic configuration A) Cr^(+3),Fe^(+3) B) Fe^(+3),Mn^(+2) C) Fe^(+3),Co^(+3) D) Sc^(+3),Cr^(+3)

    A
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    B
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    A
    `[MnO_(4)]^(-)`
    B
    `[CO(NH_(3))_(6)]^(3+)`
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