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In the complex [Co(NH3)(6)][CdClx] the o...

In the complex `[Co(NH_3)_(6)][CdCl_x]` the oxidation number of cobalt is +3 . The value of x is

A

3

B

4

C

2

D

5

Text Solution

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The correct Answer is:
To solve the problem, we need to determine the value of \( x \) in the complex \([Co(NH_3)_6][CdCl_x]\) given that the oxidation number of cobalt (Co) is +3. ### Step-by-Step Solution: 1. **Identify the oxidation states:** - The oxidation state of cobalt (Co) is given as +3. - Ammonia (NH₃) is a neutral ligand, which means it has an oxidation state of 0. - Cadmium (Cd) is in Group 12 of the periodic table and typically has an oxidation state of +2. - Chloride (Cl) has an oxidation state of -1. 2. **Set up the equation for the overall charge:** - The overall charge of the complex ion \([Co(NH_3)_6]^{3+}\) is +3 (due to Co). - The charge of the cadmium complex \([CdCl_x]\) must balance the charge from the cobalt complex to make the entire compound neutral. 3. **Write the expression for the charge balance:** - The charge contributed by the cadmium ion is +2. - The charge contributed by \( x \) chloride ions is \( -1 \times x \). - Therefore, the total charge from the cadmium complex is \( +2 - x \). 4. **Set the total charge to zero:** - Since the overall complex must be neutral, we can write the equation: \[ +3 + (2 - x) = 0 \] 5. **Solve for \( x \):** - Rearranging the equation gives: \[ 3 + 2 - x = 0 \] \[ 5 - x = 0 \] \[ x = 5 \] 6. **Conclusion:** - The value of \( x \) is 5. ### Final Answer: The value of \( x \) is 5.
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Knowledge Check

  • The name of the complex [Pt(NH_3)_6]Cl_4 is

    A
    hexaammineplatinum (IV) chloride
    B
    hexaammineplatinum (II) chloride
    C
    tetrachlorohexaammineplatinum (IV)
    D
    tetrachlorohexaammineplatinum (II).
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