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Why AlCl3 exist as dimers?...

Why `AlCl_3` exist as dimers?

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Boron chloride do not form dimers where as Aluminium chloride exist as dimers. Do you agree with this statement? Substantiate your answer.

Why does formic acid exist as dimer? What is its one consequence?

Knowledge Check

  • BCl_3 does not exist as a dimer but BH_3 exists as B_2H_6 because:

    A
    Chlorine is more electronegative than hydrogen
    B
    Large size of chlorine atom does not fit between small, sized boron atoms, while small-sized hydrogen atoms occupy the space between boron atoms.
    C
    There is `p pi-p pi` back bonding in `BCl_3`.
    D
    Both (B) and (c)

  • BCl_3 does not exist as a dimer but BH_4 exists as B_2H_6 because:

    A
    Chlorine is more electronegative than hydrogen
    B
    Large size of chlorine atom does not fit between small, sized boron atoms, while small-sized hydrogen atoms occupy the space between boron atoms.
    C
    There is `p pi - p pi` back bonding in`BCl_3`.
    D
    Both (B) and (C )

  • A compound exists in the gaseous state both as monomer ( A_(1) ) and dimer ( A_(2) ). The molecular weight of the monomer is 48. In an experiment, 96 g of the compound was confined in vessel of volume 33.6 L and heated to 273^(@) C. Calculate the pressure developed, if the compound exists as a dimer to the extent of 50% by weight under these conditions.

    A
    7.5 atm
    B
    2.0 atm
    C
    0.9 atm
    D
    5.4 atm

    • Similar Questions

    Explore conceptually related problems

    A compound exist in gaseous state both as monomer and dimer. The molecular mass of monomer is 48. In an experiment 96 g of the compound was taken in a vessel of volume 33.6 L at 273 K. What is the pressure developed if the compound exist as a dimer to an extend of 50% by mass?

    A compound exists in the gaseous state both as monomer (A_1) and dimer (A_2) . The molecular weight of the monomer is 48. In an experiment, 96 g of the compound was confined in vessel of volume 33.6L and heated to 273^(@)C . Calculate the pressure developed, if the compound exists as a dimer to the extent of 50% by weight under these conditions.

    Aluminium chloride exists as a dimer, Al_2Cl_6 in solid state as well as in solution of non-polar solvents such as benzene. When dissolved in water, it gives:

    Aluminium chloride exists as a dimer, Al_2Cl_6 in solid state as well as in solution of non-polar solvents such as benzene. When dissolved in water, it gives:

    Aluminium chloride exits as a dimer because aluminium has:

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