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Assertion : [Co(NO(2))3(NH3)3] does not ...

Assertion : `[Co(NO_(2))_3(NH_3)_3]` does not show optical isomerism.
Reason : It has a plane of symmetry.

A

If both (A) and (R) are correct and (R) is the correct explanation of (A).

B

If both (A) and (R) are correct, but (R) is not the correct explanation of (A).

C

If (A) is correct, but(R) is incorrect.

D

If both (A) and (R) are.incorrect.

Text Solution

Verified by Experts

The correct Answer is:
B

Optical isomerism is formed in octahedral complexes with 1, 2 or 3 symmetrical bidentate ligands only. Since given compound is not having any bidentate ligand, it will not show optical isomerism because it has plane of symmetry.
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Knowledge Check

  • [Co(NH_3)_4 (NO_2)_2 ] Cl exhibits

    A
    ionization isomerim, geometrical isomerism and optical isomerism
    B
    linkage isomerism, geometrical isomerisin and optical iosmerisin
    C
    linkage isomerism, ionization isomerism and optical isomerism
    D
    linkage isomerism, ionization isomerism and geometrical isomerism
  • [Co(NH_3)_4, (NO_2)_2]Cl exhibits

    A
    ionization isomerim, geometrical isomerism and optical isomerism
    B
    linkage isomerişma, geometrical isomerism and optical iosmerism
    C
    linkage isomerism, ionization isomerism and optical isomerism .
    D
    linkage isomerism, ionization isomerism and geometrical isomerism
  • Statement1 : Meso tartaric acid is optically inactive Statement 2 : Meso tartaric acid has plane of symmetry.

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    Statement 1 is True, statement 2 is True, Statement 2 is Correct explanation for Statement 4
    B
    Statement 1 is True, Statement 2 is True, Statement 2 is NOT a correct explanation for Statement 4
    C
    Statement 1 is True, Statement 2 is False.
    D
    Statement 1 is False, Statement 2 is True.
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