Home
Class 12
CHEMISTRY
Assertion : F-F bond has low bond disso...

Assertion : F-F bond has low bond dissociation
Reason : The fluorine has lower reactivity.

A

If both the assertion and reason are true and reason is correct explanation of the assertion .

B

If both the assertion and reason are true but reason is not a correct explanation of the assertion .

C

If the assertion is true but the reason is false.

D

If both assertion and reason are false.

Text Solution

Verified by Experts

The correct Answer is:
C

Lower value of bod bond dissociaton energy of fluorine is due to the high inter electronic repulsions between non-bonding electron of the 2p-orbital of small sized fluorine . As a result F-F bond is weaker as comparison to Cl-Cl and Br-Br bonds .
Bond dissociation energy
`{:("F-F 38 K cal / mole "),(Cl-Cl" 57K cal/mole"),(Br-Br" 45.5 K cal/mole"),(I-I" 35.6 K cal/mole"):}`
Doubtnut Promotions Banner Mobile Dark
|

Similar Questions

Explore conceptually related problems

Define bond dissociation energy.

Assertion (A): The flourine has lower reactivity. Reason (R ): F-F bond has low bond dissociation energy. If both (A) and (R) are correct, and (R) is the correct explanation of (A) If both (A) and (R) are correct, but (R) is not the correct explanation of (A). If (A) is correct, but (R) is incorrect. If (A) is incorrect, but (R) is correct.

Assertion : Fluorine is a stronger oxidizing agent than iodine. Reason : Fluorine has greater electronegativity than iodine.

Assertion : Bond energy and bond dissociation energy have identical value for diatomic molecules. Reason : Greater the bond dissociation energy, less reactive is the bond.

Assertion : bond dissociation energy of N-F bond in NF_(3) molecule is lower than that of in NCl_(3) molecule. Reason : Interelectronic repulsion exists between small size N and F atoms N-F bond of NF_(2) molecule.

Assertion : bond dissociation energy of N-F bond in NF_(3) molecule is lower than that of in NCl_(3) molecule. Reason : Interelectronic repulsion exists between small size N and F atoms N-F bond of NF_(3) molecule.

Assertion :- Low concentration of oxygen allow dissociation of oxyhaemoglobin. Reason :- CO has more affinity with Haemoglobin as compares to oxygen.

Assertion : sigma -bond is strong white pi -bond is a weak bond. Reason :Atomic rotate freely about pi -bond.

Assertion: Fluorine exists only in -1 oxidation state. Reason: Fluorine has 2s^(2)2p^(5) configuration.

Assertion (A): F_(2) undergoes disproportionation reaction. Reason (R ): Fluorine shows both positive and negative oxidation states.