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Assertion: Benzyl bromide when kept in a...

Assertion: Benzyl bromide when kept in acetone water produces benzyl alcohol.
Reason: The reaction follows `S_(N)2` mechanism.

A

If the both assertion and reason are true and the reason is the correct explanation of the assertion

B

If both assertion and reason are true and the reason is not the correct explanation of the assertion

C

If assertion is true but reason is false

D

If both assertion and reason are false statements.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question, we need to analyze the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that benzyl bromide, when kept in acetone-water, produces benzyl alcohol. - Benzyl bromide (C6H5CH2Br) is a primary alkyl halide. 2. **Reaction Conditions**: - The solvent used is a mixture of acetone and water. Acetone is a polar aprotic solvent, while water is a polar protic solvent. This combination can facilitate nucleophilic substitution reactions. 3. **Mechanism of Reaction**: - The reaction proceeds via an `S_N2` mechanism. In this mechanism, a nucleophile attacks the electrophilic carbon atom bonded to the bromine atom, leading to the displacement of the bromine atom. - In this case, water (H2O) acts as the nucleophile. The oxygen atom in water has lone pairs of electrons that can attack the carbon atom. 4. **Reaction Process**: - The nucleophilic attack occurs as follows: - The oxygen atom of water attacks the carbon atom of benzyl bromide. - The C-Br bond breaks, and bromide ion (Br-) is released. - This results in the formation of benzyl alcohol (C6H5CH2OH). 5. **Final Product**: - The final product of the reaction is indeed benzyl alcohol, confirming the assertion. 6. **Understanding the Reason**: - The reason states that the reaction follows the `S_N2` mechanism. - Since benzyl bromide is a primary alkyl halide, it is more likely to undergo `S_N2` reactions rather than `S_N1` reactions, which are more common for tertiary alkyl halides. 7. **Conclusion**: - Both the assertion and the reason are true, and the reason correctly explains the assertion. ### Final Answer: Both assertion and reason are true. The reason is the correct explanation of the assertion.

To solve the given question, we need to analyze the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that benzyl bromide, when kept in acetone-water, produces benzyl alcohol. - Benzyl bromide (C6H5CH2Br) is a primary alkyl halide. ...
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Knowledge Check

  • Assertion: The order of reactivity of alkyl halides towards S_(N^1) reaction in tertiary halidegtsecondary halidegtprimary halide. Reason: The reaction follows carbocation mechanism.

    A
    If both assertion and reason are true and reason Is the correct explanation of assertion.
    B
    If both assertion and reason are true but reason is not the correct explanation of assertion.
    C
    If assetion is true but reason is false.
    D
    If both assertion and reason are false.
  • What is the product ofthe following S_(N^2) reaction?

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    D
  • Which of the following are S_(N)2 reactions?

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    C
    D
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