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Assertion (A) The magnetic moment (mu) o...

Assertion (A) The magnetic moment `(mu)` of an electron revolving around the nucleus decreases with increasing principle quantum number (n).
Reason (R ) Magnetic moment of the revolving electron , `muprop` n.

A

If both Assertion and Reason are true and Reason is correct explanation of Assertion.

B

If both Assertion and Reason are true but Reason is not the correct explanation of Assertion.

C

If Assertion is true but Reason is false.

D

If both Assertion and Reason are false.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the assertion and reason provided in the question regarding the magnetic moment of an electron revolving around the nucleus. ### Step-by-Step Solution: 1. **Understanding Magnetic Moment**: The magnetic moment (μ) of an electron in a circular orbit can be expressed as: \[ \mu = I \cdot A \] where \(I\) is the current and \(A\) is the area of the orbit. 2. **Current Calculation**: The current \(I\) due to the revolving electron can be calculated as: \[ I = \frac{e}{T} \] where \(e\) is the charge of the electron and \(T\) is the time period of one complete revolution. The time period \(T\) can be expressed as: \[ T = \frac{2\pi r}{v} \] where \(r\) is the radius of the orbit and \(v\) is the velocity of the electron. 3. **Area Calculation**: The area \(A\) of the circular orbit is given by: \[ A = \pi r^2 \] 4. **Substituting Current and Area into Magnetic Moment**: Now substituting \(I\) and \(A\) into the magnetic moment formula: \[ \mu = I \cdot A = \left(\frac{e}{T}\right) \cdot \pi r^2 \] Substituting \(T\): \[ \mu = \left(\frac{e}{\frac{2\pi r}{v}}\right) \cdot \pi r^2 = \frac{e v r}{2} \] 5. **Using Bohr's Postulate**: According to Bohr's postulate, the angular momentum \(L\) of the electron is quantized: \[ L = mvr = n \frac{h}{2\pi} \] where \(n\) is the principal quantum number and \(h\) is Planck's constant. 6. **Expressing Velocity in Terms of Quantum Number**: From the angular momentum equation, we can express \(vr\) as: \[ vr = \frac{n h}{2\pi m} \] 7. **Substituting Back to Magnetic Moment**: Now substituting \(vr\) back into the expression for magnetic moment: \[ \mu = \frac{e}{2} \cdot \frac{n h}{2\pi m} = \frac{e n h}{4\pi m} \] This shows that the magnetic moment \(\mu\) is directly proportional to the principal quantum number \(n\): \[ \mu \propto n \] 8. **Conclusion**: - The assertion states that the magnetic moment decreases with increasing principal quantum number \(n\), which is **incorrect**. - The reason states that the magnetic moment is proportional to \(n\), which is **correct**. ### Final Answer: - Assertion (A) is **false**. - Reason (R) is **true**.
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