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Assertion : bond angle H2O is less than...

Assertion : bond angle H2O is less than the normal tetrahedral bond angle.
Reason : Lone pair-lone pair repulsion decreases bond angle.

A

If both assertion and reason are true and reason is the correct explanation of assertion.

B

If both assertion and reason are true but reason is not the correct explanation of assertion.

C

If assertion is true but reason is false.

D

If both assertion and reason are false.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that the bond angle in H2O (water) is less than the normal tetrahedral bond angle (which is approximately 109.5 degrees). - In water, the bond angle is actually about 104.5 degrees. 2. **Understanding the Reason**: - The reason given is that "lone pair-lone pair repulsion decreases bond angle." - In the case of water, the oxygen atom has two lone pairs and forms two bonds with hydrogen atoms. 3. **Analyzing the Molecular Geometry**: - The molecular geometry of water can be described as bent or V-shaped due to the presence of two lone pairs on the oxygen atom. - The hybridization of the oxygen in water is sp3, which typically has a tetrahedral arrangement of electron pairs. 4. **Effect of Lone Pairs on Bond Angles**: - In a tetrahedral arrangement, the ideal bond angle is 109.5 degrees. However, lone pairs occupy more space than bonding pairs, leading to greater repulsion. - This increased repulsion from the lone pairs pushes the bonding pairs closer together, resulting in a smaller bond angle. 5. **Conclusion**: - Since the bond angle in H2O is indeed less than the normal tetrahedral bond angle due to the presence of lone pairs, both the assertion and reason are correct. - Furthermore, the reason provided correctly explains why the bond angle is less than the tetrahedral angle. ### Final Answer: - Assertion: True - Reason: True - The reason is the correct explanation for the assertion.
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