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A compound that gives positive iodoform ...

A compound that gives positive iodoform test is

A

1-pentanol

B

2-pentanone

C

3-pentanone

D

pentanal

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The correct Answer is:
To determine which compound gives a positive iodoform test, we need to identify compounds that contain the specific structural unit that can lead to this reaction. The iodoform test is positive for compounds that have the structure RCOCH3 (where R can be any alkyl group) or for secondary alcohols that can be oxidized to such ketones. ### Step-by-Step Solution: 1. **Understanding the Iodoform Test**: - The iodoform test is used to identify the presence of a methyl ketone (RCOCH3) or a secondary alcohol that can be oxidized to a methyl ketone. 2. **Analyzing the Options**: - We will analyze each of the given compounds to see if they can give a positive iodoform test. 3. **Option 1: 1-Pentanol (C5H12O)**: - Structure: CH3-CH2-CH2-CH2-CH2-OH - Upon oxidation, 1-pentanol will convert to pentanal (an aldehyde), which does not have the required methyl ketone structure (RCOCH3). - **Conclusion**: 1-pentanol does not give a positive iodoform test. 4. **Option 2: 2-Pentanone (C5H10O)**: - Structure: CH3-CO-CH2-CH2-CH3 - This compound contains the structure RCOCH3 (where R is the ethyl group, CH2-CH3). - Therefore, 2-pentanone can give a positive iodoform test. - **Conclusion**: 2-pentanone gives a positive iodoform test. 5. **Option 3: 3-Pentanone (C5H10O)**: - Structure: CH3-CH2-CO-CH2-CH3 - This compound does not have the methyl group directly attached to the carbonyl carbon (C=O). - **Conclusion**: 3-pentanone does not give a positive iodoform test. 6. **Option 4: Pentanal (C5H10O)**: - Structure: CH3-CH2-CH2-CH2-CHO - This is an aldehyde and does not have the methyl ketone structure. - **Conclusion**: Pentanal does not give a positive iodoform test. ### Final Answer: The compound that gives a positive iodoform test is **2-Pentanone**. ---
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ICSE-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-EXERCISE (PART-I OBJECTIVE QUESTIONS)
  1. When acetaldehyde is heated with Fehling solution, it gives a precipit...

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  2. Cannizzaro reaction is not given by

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  3. A compound that gives positive iodoform test is

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  4. The compound oxidised to prepare methyl ethyl ketone is

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  5. The formation of cyanohydrin from a ketone is an example of

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  6. Treatment of propionaldehyde with dil. NaOH solution gives

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  7. Hydrogenation of benzoyl chloride in the presence of Pd on BaSO(4) giv...

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  8. Aldol condensation of acetaldehyde involves the formation of which of ...

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  9. Positive iodofonn test is given by

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  10. Clemmensen reduction of a ketone is carried out in presence of

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  11. Acetone on heating with conc. H(2)SO(4) mainly gives

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  12. Schiff reagent gives pink colour with

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  13. The reaction of benzaldehyde with alkali gives

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  14. The compound which does not give formaldehyde on heating or distillati...

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  15. A cyanohydrin of a compound X on hydrolysis gives lactic acid. The X i...

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  16. The reaction of formaldehyde with Grignard's reagent followed by hydro...

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  17. IUPAC name of CH(3)CH(2)CH(2)CH(CH(3))COCH(3) is

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  18. IUPAC name of CH(3)-underset(CH(3))underset(|)C=CH-underset(O)underset...

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  19. The compound which does not give iodoform test is

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  20. The compound which does not give iodoform on treatment with NaOH and i...

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