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An organic compound A(C(5)H(8)O(3)) on h...

An organic compound `A(C_(5)H_(8)O_(3))` on heating with soda lime gives B which reacts with HCN to give C. The compound C reacts with thionyl chloride to produce D which on reaction with KCN gives a coompound E. Alkaline hydrolysis of E gives a salt F which on heating with soda lime produces n-butane. Careful oxidation of A with dichromate gives acetic acid and malonic acid. Give the structures from A to F with proper reason.

Answer

Step by step text solution for An organic compound A(C_(5)H_(8)O_(3)) on heating with soda lime gives B which reacts with HCN to give C. The compound C reacts with thionyl chloride to produce D which on reaction with KCN gives a coompound E. Alkaline hydrolysis of E gives a salt F which on heating with soda lime produces n-butane. Careful oxidation of A with dichromate gives acetic acid and malonic acid. Give the structures from A to F with proper reason. by CHEMISTRY experts to help you in doubts & scoring excellent marks in Class 12 exams.

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Knowledge Check

  • Ethanol reacts with thionyl chloride to give ethyl chloride and :

    A
    `S,SO_2`
    B
    `SO_2, HCl`
    C
    `Cl_2,SO_3`
    D
    `SO_3,HCl`

  • Ethanol reacts with thionyl chloride to give ethyl chloride and :

    A
    `S,SO_2`
    B
    `SO_2,HCI`
    C
    `CI_2,SO_3`
    D
    `SO_3,HCI`

  • Sodium formate on heating with soda lime give:

    A
    `CH_4`
    B
    `H_2O`
    C
    `H_2`
    D
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