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Which of the following is diamagnetic ?...

Which of the following is diamagnetic ?

A

`H_(2)^(+)`

B

`He_(2)^(+)`

C

`O_(2)`

D

`N_(2).`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given species is diamagnetic, we will analyze the electron configurations of each species mentioned in the question. A species is considered diamagnetic if all of its electrons are paired, while it is paramagnetic if it has unpaired electrons. ### Step-by-Step Solution: 1. **Identify the Species**: The species we need to analyze are H2+, H2, O2, and N2. 2. **Analyze H2+**: - **Number of Electrons**: H2+ has 1 electron (since it is a hydrogen molecule with a positive charge). - **Electron Configuration**: The configuration is σ1s¹. - **Unpaired Electrons**: There is 1 unpaired electron. - **Conclusion**: H2+ is paramagnetic. 3. **Analyze H2**: - **Number of Electrons**: H2 has 2 electrons. - **Electron Configuration**: The configuration is σ1s². - **Unpaired Electrons**: All electrons are paired. - **Conclusion**: H2 is diamagnetic. 4. **Analyze O2**: - **Number of Electrons**: O2 has 16 electrons. - **Electron Configuration**: The configuration is σ1s² σ*1s² σ2s² σ*2s² σ2p² (with 2 unpaired electrons in the π* orbitals). - **Unpaired Electrons**: There are 2 unpaired electrons. - **Conclusion**: O2 is paramagnetic. 5. **Analyze N2**: - **Number of Electrons**: N2 has 14 electrons. - **Electron Configuration**: The configuration is σ1s² σ*1s² σ2s² σ*2s² (with 2 paired electrons in the σ2p and 4 paired electrons in the π2p orbitals). - **Unpaired Electrons**: All electrons are paired. - **Conclusion**: N2 is diamagnetic. ### Final Conclusion: Among the species analyzed, H2 and N2 are diamagnetic. However, since the question asks for "which of the following is diamagnetic," the correct answer is **N2**.

To determine which of the given species is diamagnetic, we will analyze the electron configurations of each species mentioned in the question. A species is considered diamagnetic if all of its electrons are paired, while it is paramagnetic if it has unpaired electrons. ### Step-by-Step Solution: 1. **Identify the Species**: The species we need to analyze are H2+, H2, O2, and N2. 2. **Analyze H2+**: - **Number of Electrons**: H2+ has 1 electron (since it is a hydrogen molecule with a positive charge). ...
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