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Statement 1: H(2) molecule is more stabl...

Statement 1: `H_(2)` molecule is more stable than `H_(2)-He` molecule
Statement 2: The antibonding electron in `H_(2)-He` molecule destabilizes. It.

A

Statement-1 is true, Statement-2 is also true, Statement -2 is the correct explanation of statement-2

B

Statement -1 is true , Statement 2 is also true, Statement-2 is not the correct ezplanation of Statement-2

C

Statement-1 is true, Statement-2 is false.

D

Statement-1 is false, Statement-2 is true.

Text Solution

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The correct Answer is:
To analyze the statements regarding the stability of the H₂ molecule compared to the H₂-He molecule, we will follow these steps: ### Step 1: Understanding Molecular Orbitals - **H₂ Molecule**: The H₂ molecule consists of two hydrogen atoms, each contributing one electron. When these atomic orbitals combine, they form one bonding molecular orbital (σ1s) and one antibonding molecular orbital (σ*1s). The electronic configuration for H₂ is: - Bonding electrons: 2 (in σ1s) - Antibonding electrons: 0 (in σ*1s) - **He₂ Molecule**: The He₂ molecule consists of two helium atoms, each contributing two electrons. The electronic configuration for He₂ is: - Bonding electrons: 2 (in σ1s) - Antibonding electrons: 2 (in σ*1s) ### Step 2: Calculating Bond Order - **Bond Order Formula**: The bond order can be calculated using the formula: \[ \text{Bond Order} = \frac{1}{2} (\text{Number of Bonding Electrons} - \text{Number of Antibonding Electrons}) \] - **For H₂**: \[ \text{Bond Order} = \frac{1}{2} (2 - 0) = 1 \] - **For He₂**: \[ \text{Bond Order} = \frac{1}{2} (2 - 2) = 0 \] ### Step 3: Stability of Molecules - A bond order of 1 for H₂ indicates that it is a stable molecule with one bond. - A bond order of 0 for He₂ indicates that it is unstable and does not exist as a molecule. ### Step 4: Evaluating Statements - **Statement 1**: "H₂ molecule is more stable than H₂-He molecule." - This statement is true because H₂ has a bond order of 1 (stable), while H₂-He (or He₂) has a bond order of 0 (unstable). - **Statement 2**: "The antibonding electron in H₂-He molecule destabilizes it." - This statement is also true because the presence of two electrons in the antibonding molecular orbital (σ*1s) leads to a bond order of 0, indicating instability. ### Conclusion Both statements are true, and the second statement correctly explains the first. ### Final Answer Both Statement 1 and Statement 2 are true. ---

To analyze the statements regarding the stability of the H₂ molecule compared to the H₂-He molecule, we will follow these steps: ### Step 1: Understanding Molecular Orbitals - **H₂ Molecule**: The H₂ molecule consists of two hydrogen atoms, each contributing one electron. When these atomic orbitals combine, they form one bonding molecular orbital (σ1s) and one antibonding molecular orbital (σ*1s). The electronic configuration for H₂ is: - Bonding electrons: 2 (in σ1s) - Antibonding electrons: 0 (in σ*1s) - **He₂ Molecule**: The He₂ molecule consists of two helium atoms, each contributing two electrons. The electronic configuration for He₂ is: ...
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