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A metal crystallizes with a body-centred...

A metal crystallizes with a body-centred cubic lattice. The length of the unit cell edge is found to be `265`pm. Calculate the atomic radius.

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To calculate the atomic radius of a metal that crystallizes in a body-centered cubic (BCC) lattice with a unit cell edge length of 265 pm, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure**: - In a body-centered cubic (BCC) lattice, there are atoms located at each of the eight corners of the cube and one atom at the center of the cube. 2. **Understand the Body Diagonal**: - The body diagonal of the cube runs from one corner of the cube to the opposite corner. In a BCC structure, this diagonal contains three atomic radii (R) from the corner atom, the center atom, and the other corner atom. 3. **Calculate the Length of the Body Diagonal**: - The length of the body diagonal (d) can be expressed in terms of the edge length (a) of the cube: \[ d = a\sqrt{3} \] - Here, \( a = 265 \) pm. 4. **Relate the Body Diagonal to Atomic Radii**: - The body diagonal is equal to the sum of the atomic radii along the diagonal: \[ d = 4R \] - This is because the body diagonal consists of one radius from each of the two corner atoms and one radius from the center atom, totaling four radii. 5. **Set Up the Equation**: - Combine the two equations: \[ 4R = a\sqrt{3} \] 6. **Solve for the Atomic Radius (R)**: - Rearranging the equation gives: \[ R = \frac{a\sqrt{3}}{4} \] - Substitute the value of \( a \): \[ R = \frac{265 \times \sqrt{3}}{4} \] 7. **Calculate the Value**: - First, calculate \( \sqrt{3} \approx 1.732 \): \[ R = \frac{265 \times 1.732}{4} \approx \frac{459.58}{4} \approx 114.895 \text{ pm} \] 8. **Final Result**: - The atomic radius \( R \) is approximately \( 114.895 \) pm. ### Final Answer: The atomic radius of the metal is approximately **114.895 pm**.

To calculate the atomic radius of a metal that crystallizes in a body-centered cubic (BCC) lattice with a unit cell edge length of 265 pm, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure**: - In a body-centered cubic (BCC) lattice, there are atoms located at each of the eight corners of the cube and one atom at the center of the cube. 2. **Understand the Body Diagonal**: ...
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Knowledge Check

  • Chromium metal crystallizes with a body-centred cubic lattice. The length of the unit cell edge is found to be 287 pm. Calculate the atomic radius. What woulds be the density of chromium in g cm^(-3) ?

    A
    124.27 pm
    B
    287 pm
    C
    574 pm
    D
    143.5 pm
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