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Assertion (A) : CsCl crystal, the coordi...

Assertion (A) : `CsCl` crystal, the coordination number of `Cs^(o+)` ion is `8`.
Reason (R ) : `Cl^(ɵ)` ion in `CsCl` adopt bcc type of packing,

A

If both assertion and reason are correct and reason is correct explanation for assertion

B

If both assertion and reason are correct but reason is not correct explanation for assertion

C

If assertion is correct but reason is incorrect

D

If both assertion and reason are incorrect

Text Solution

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The correct Answer is:
To analyze the given assertion and reason regarding the CsCl crystal structure, we can break down the solution into several steps: ### Step-by-Step Solution 1. **Understanding the Assertion**: - The assertion states that in a CsCl crystal, the coordination number of the Cs⁺ ion is 8. - Coordination number refers to the number of nearest neighbor ions surrounding a central ion. 2. **Analyzing the CsCl Structure**: - CsCl crystallizes in a body-centered cubic (BCC) lattice structure. - In this structure, the Cs⁺ ions occupy the body center of the cube, while the Cl⁻ ions are located at the corners of the cube. 3. **Determining the Coordination Number**: - In a BCC lattice, the body-centered atom (Cs⁺) is surrounded by 8 corner atoms (Cl⁻). - Therefore, the coordination number of the Cs⁺ ion is indeed 8, as it is in contact with the 8 Cl⁻ ions located at the corners. 4. **Understanding the Reason**: - The reason states that the Cl⁻ ion in CsCl adopts BCC type of packing. - However, this statement is incorrect because the Cl⁻ ions only occupy the corners of the cube, which corresponds to a simple cubic (SCC) packing, not BCC. 5. **Conclusion**: - The assertion is true because the coordination number of Cs⁺ is 8. - The reason is false because Cl⁻ does not adopt BCC packing; it adopts SCC packing. - Therefore, the correct conclusion is that the assertion is correct, but the reason is incorrect. ### Final Answer - The assertion is true, and the reason is false.

To analyze the given assertion and reason regarding the CsCl crystal structure, we can break down the solution into several steps: ### Step-by-Step Solution 1. **Understanding the Assertion**: - The assertion states that in a CsCl crystal, the coordination number of the Cs⁺ ion is 8. - Coordination number refers to the number of nearest neighbor ions surrounding a central ion. ...
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Knowledge Check

  • In CsCI lattice the coordination number of Cs ion is

    A
    8,8
    B
    4,4
    C
    6,6
    D
    8,4
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