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The most effective pair of reagents for ...

The most effective pair of reagents for the preparation of tert bytyl ethyl ehter is :

A

potassium tert-bytoxide and ethyl bromide

B

potassium tert-butoxide and ethanol

C

sodium ethxoide and tert-butyl bromide.

D

tert-butyl alcohol and ethyl bromide.

Text Solution

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The correct Answer is:
To prepare tert-butyl ethyl ether, we can use the Williamson synthesis method. This method involves the reaction of an alkoxide with a primary alkyl halide. Here’s a step-by-step solution: ### Step 1: Identify the Required Ether We need to prepare tert-butyl ethyl ether. The structure of tert-butyl ethyl ether can be represented as: - tert-butyl group: (CH₃)₃C- - ethyl group: CH₃CH₂- ### Step 2: Choose the Alkoxide To create tert-butyl ethyl ether, we need to form an alkoxide from tert-butyl alcohol (tert-butanol). The alkoxide ion is formed by deprotonating tert-butanol: - tert-butanol (C₄H₁₀O) reacts with a strong base (like sodium hydride or sodium metal) to form tert-butoxide (C₄H₉O⁻). ### Step 3: Choose the Alkyl Halide Next, we need an alkyl halide to react with the alkoxide. For the ethyl part of the ether, we can use ethyl bromide (C₂H₅Br) as the alkyl halide. ### Step 4: Perform the Reaction The reaction involves the nucleophilic attack of the tert-butoxide ion on the ethyl bromide: - tert-butoxide (C₄H₉O⁻) attacks the ethyl bromide (C₂H₅Br) via an SN2 mechanism, leading to the formation of tert-butyl ethyl ether (C₄H₉OC₂H₅) and the release of bromide ion (Br⁻). ### Step 5: Write the Overall Reaction The overall reaction can be summarized as: \[ \text{C₄H₉OH (tert-butanol) + Na → C₄H₉O⁻ (tert-butoxide) + NaBr} \] \[ \text{C₄H₉O⁻ + C₂H₅Br → C₄H₉OC₂H₅ (tert-butyl ethyl ether) + Br⁻} \] ### Conclusion Thus, the most effective pair of reagents for the preparation of tert-butyl ethyl ether is: - **tert-butyl alcohol (C₄H₉OH)** and **ethyl bromide (C₂H₅Br)**.

To prepare tert-butyl ethyl ether, we can use the Williamson synthesis method. This method involves the reaction of an alkoxide with a primary alkyl halide. Here’s a step-by-step solution: ### Step 1: Identify the Required Ether We need to prepare tert-butyl ethyl ether. The structure of tert-butyl ethyl ether can be represented as: - tert-butyl group: (CH₃)₃C- - ethyl group: CH₃CH₂- ### Step 2: Choose the Alkoxide ...
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