Home
Class 12
CHEMISTRY
Carbonyl compounds undergo nucleophilic ...

Carbonyl compounds undergo nucleophilic addition because of :

A

electronegativity difference of carbon and oxygen atoms

B

electromeric effect.

C

more stable anion with negative charge on oxygen and less stables carbocation

D

none of these

Text Solution

AI Generated Solution

The correct Answer is:
To answer the question "Carbonyl compounds undergo nucleophilic addition because of:", we need to analyze the properties of carbonyl compounds and the nature of the nucleophilic addition reaction. ### Step-by-Step Solution: 1. **Understanding Carbonyl Compounds**: - Carbonyl compounds contain a carbonyl group (C=O), which is a functional group consisting of a carbon atom double-bonded to an oxygen atom. 2. **Polarity of the Carbonyl Group**: - The carbon-oxygen bond in carbonyl compounds is polar due to the difference in electronegativity between carbon and oxygen. Oxygen is more electronegative than carbon, which means it attracts the shared electrons more strongly. 3. **Partial Charges**: - Because of this polarity, the carbon atom in the carbonyl group acquires a partial positive charge (δ+), while the oxygen atom acquires a partial negative charge (δ-). This creates a dipole moment in the molecule. 4. **Nucleophilic Attack**: - Nucleophiles are species that have a negative charge or a lone pair of electrons and are attracted to positively charged or partially positively charged centers. In carbonyl compounds, the partially positive carbon atom acts as an electrophile, making it susceptible to attack by nucleophiles. 5. **Formation of Tetrahedral Intermediate**: - When a nucleophile attacks the carbon atom of the carbonyl group, it forms a tetrahedral intermediate. This is a key step in the nucleophilic addition mechanism. 6. **Stability Considerations**: - The reaction is favored because the resulting anion (after the nucleophile adds to the carbonyl carbon) is more stable than a carbocation that would form if the carbonyl compound were to undergo a different type of reaction. The negative charge is stabilized on the more electronegative oxygen atom. 7. **Conclusion**: - Therefore, carbonyl compounds undergo nucleophilic addition due to the polar nature of the carbonyl group, which creates a favorable condition for nucleophilic attack, leading to the formation of a more stable anion. ### Final Answer: Carbonyl compounds undergo nucleophilic addition because of the polar nature of the carbon-oxygen bond, which results in a partial positive charge on the carbon atom, making it susceptible to nucleophilic attack, and because the resulting anion is more stable than a carbocation.

To answer the question "Carbonyl compounds undergo nucleophilic addition because of:", we need to analyze the properties of carbonyl compounds and the nature of the nucleophilic addition reaction. ### Step-by-Step Solution: 1. **Understanding Carbonyl Compounds**: - Carbonyl compounds contain a carbonyl group (C=O), which is a functional group consisting of a carbon atom double-bonded to an oxygen atom. 2. **Polarity of the Carbonyl Group**: ...
Doubtnut Promotions Banner Mobile Dark
|

Similar Questions

Explore conceptually related problems

The order of reactivity of carbonyl compounds for nucleophilic addition is

Discuss the relative reactivities of carbonyl compounds in nucleophilic addition reactions.

Aldehyde and ketones are specially susceptible susceptible to nucleophile addition because carbonyl group (due to electronegatvity different between carbon and oxygen). Positive charge on carbon makes it reactive towards the nucleophile. This addition is catalysed by acid. Reactivity of carbonyl compound towards nucleophilic addition increases in the electron deficience at carbonyl carbon. Thus, (-I.E.) group increase while (+I.E.) groups decrease the reactivity of carbonyl compound Carbonyl compounds show nucleophilic addition with:

Aldehyde and ketones are specially susceptible susceptible to nucleophile addition because carbonyl group (due to electronegatvity different between carbon and oxygen). Positive charge on carbon makes it reactive towards the nucleophile. This addition is catalysed by acid. Reactivity of carbonyl compound towards nucleophilic addition increases in the electron deficience at carbonyl carbon. Thus, (-I.E.) group increase while (+I.E.) groups decrease the reactivity of carbonyl compound Select the least reactive carbonyl compound for nucleophilic addition:

The reactivity of carbonyl compounds towards nucleophilic addition reaction gets affected by

Aldehyde and ketones are specially susceptible susceptible to nucleophile addition because carbonyl group (due to electronegatvity different between carbon and oxygen). Positive charge on carbon makes it reactive towards the nucleophile. This addition is catalysed by acid. Reactivity of carbonyl compound towards nucleophilic addition increases in the electron deficience at carbonyl carbon. Thus, (-I.E.) group increase while (+I.E.) groups decrease the reactivity of carbonyl compound Which of the following is most reactve to give nucleophilic addition?

Aldehyde and ketones are specially susceptible susceptible to nucleophile addition because carbonyl group (due to electronegatvity different between carbon and oxygen). Positive charge on carbon makes it reactive towards the nucleophile. This addition is catalysed by acid. Reactivity of carbonyl compound towards nucleophilic addition increases in the electron deficience at carbonyl carbon. Thus, (-I.E.) group increase while (+I.E.) groups decrease the reactivity of carbonyl compound Which among the following carbonyl compounds is most polar?

Aldehyde and ketones are specially susceptible susceptible to nucleophile addition because carbonyl group (due to electronegatvity different between carbon and oxygen). Positive charge on carbon makes it reactive towards the nucleophile. This addition is catalysed by acid. Reactivity of carbonyl compound towards nucleophilic addition increases in the electron deficience at carbonyl carbon. Thus, (-I.E.) group increase while (+I.E.) groups decrease the reactivity of carbonyl compound

Aldehydes and ketones are amphoteric. Thus they can act both as acids and bases. Under acidic conditions, the carbon of the protonated canbonyl group is much more electrophilic, reacting even with weak nucleopphilie. Carbonyl compound gives nucleophilic addition reaction. In this reaction the nucleophilic attack proceeds the elecrophilic attack. Carbonyl compounds gives nucleophilic addition with

Assertion : Carbonyl compounds take part in nucleophilic addition reactions. Reason : These reactions are initiated by nucleophilic attack at the electron deficient carbon atom.