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n moles of an ideal triatomic linear gas...

n moles of an ideal triatomic linear gas undergoes a process in which the temperature changes with volume as `k_(1)V ^ 2` where `k_(1)` is a constant. Choose incorrect alternative.

A

At normal temperature `C_(v)=(5)/(2)R`

B

At any temperature `C_(p)-C_(v)=R`

C

At normal temperature molar heat capacity C=3R

D

At any temperature molar heat capacity C=3R

Text Solution

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The correct Answer is:
To solve the problem, we need to analyze the given statements about the ideal triatomic linear gas undergoing a process where the temperature varies with volume as \( T = k_1 V^2 \). We will evaluate each statement to identify the incorrect one. ### Step-by-Step Solution: 1. **Understanding the Degrees of Freedom**: - For a triatomic linear gas, the degrees of freedom \( F \) is given by \( F = 5 \) (3 translational + 2 rotational). - Therefore, the molar heat capacity at constant volume \( C_v \) can be calculated as: \[ C_v = \frac{F}{2} R = \frac{5}{2} R \] 2. **Evaluating the First Statement**: - The first statement claims that at normal temperature, \( C_v = \frac{5}{2} R \). - Since we have calculated \( C_v \) as \( \frac{5}{2} R \), this statement is **correct**. 3. **Evaluating the Second Statement**: - The second statement states that \( C_p - C_v = R \). - We know that for any ideal gas, this relation holds true. Thus: \[ C_p = C_v + R = \frac{5}{2} R + R = \frac{7}{2} R \] - Therefore, \( C_p - C_v = R \) is also **correct**. 4. **Evaluating the Third Statement**: - The third statement claims that at normal temperature, the molar heat capacity \( C = 3R \). - We need to check if the molar heat capacity \( C \) can be derived from the process \( T = k_1 V^2 \) and the ideal gas equation \( PV = nRT \). - Using the relation derived from the process and the ideal gas law, we find: \[ C = C_v + R = \frac{5}{2} R + R = \frac{7}{2} R \] - This means that the statement claiming \( C = 3R \) is **incorrect**. 5. **Evaluating the Fourth Statement**: - The fourth statement claims that at any temperature, the molar heat capacity \( C = 3R \). - Since we have established that \( C = \frac{7}{2} R \) at normal conditions and it does not hold for all temperatures, this statement is also **incorrect**. ### Conclusion: The incorrect statement is the third one, which states that at normal temperature, the molar heat capacity \( C = 3R \).

To solve the problem, we need to analyze the given statements about the ideal triatomic linear gas undergoing a process where the temperature varies with volume as \( T = k_1 V^2 \). We will evaluate each statement to identify the incorrect one. ### Step-by-Step Solution: 1. **Understanding the Degrees of Freedom**: - For a triatomic linear gas, the degrees of freedom \( F \) is given by \( F = 5 \) (3 translational + 2 rotational). - Therefore, the molar heat capacity at constant volume \( C_v \) can be calculated as: \[ ...
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