Home
Class 12
CHEMISTRY
For the water gas reaction C(s)+H(2)O(...

For the water gas reaction
`C(s)+H_(2)O(g)hArrCO(g)+H_(2)(g)`
The standard Gibb's energy of energy of reaction (at 1000K) is `-8.1KJmol^(-1)`. Value of equilibrium constant is -

A

2.6

B

6.2

C

8.2

D

10

Text Solution

AI Generated Solution

The correct Answer is:
To find the equilibrium constant (K) for the water gas reaction given the standard Gibbs energy change (ΔG°) at 1000 K, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the relationship between ΔG° and K**: The relationship between the standard Gibbs energy change (ΔG°) and the equilibrium constant (K) is given by the equation: \[ \Delta G^\circ = -2.303RT \log K \] 2. **Rearrange the equation to solve for log K**: We can rearrange the equation to isolate log K: \[ \log K = \frac{-\Delta G^\circ}{2.303RT} \] 3. **Substitute the known values**: We know: - ΔG° = -8.1 kJ/mol = -8.1 × 10³ J/mol (convert kJ to J) - R (gas constant) = 8.314 J/(K·mol) - T (temperature) = 1000 K Substituting these values into the equation: \[ \log K = \frac{-(-8.1 \times 10^3)}{2.303 \times 8.314 \times 1000} \] 4. **Calculate the denominator**: First, calculate the denominator: \[ 2.303 \times 8.314 \times 1000 = 19115.982 \] 5. **Calculate log K**: Now substitute back into the equation: \[ \log K = \frac{8.1 \times 10^3}{19115.982} \approx 0.423 \] 6. **Find K**: To find K, we use the antilogarithm: \[ K = 10^{0.423} \approx 2.63 \] 7. **Round the answer**: Rounding to one decimal place, we get: \[ K \approx 2.6 \] ### Final Answer: The value of the equilibrium constant (K) is approximately **2.6**.

To find the equilibrium constant (K) for the water gas reaction given the standard Gibbs energy change (ΔG°) at 1000 K, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the relationship between ΔG° and K**: The relationship between the standard Gibbs energy change (ΔG°) and the equilibrium constant (K) is given by the equation: \[ \Delta G^\circ = -2.303RT \log K ...
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • CHEMISTRY AT A GLANCE

    ALLEN|Exercise INORGANIC CHEMISTRY|300 Videos
  • CHEMISTRY AT A GLANCE

    ALLEN|Exercise ORGANIC CHEMISTRY|472 Videos
  • Chemical Equilibrium

    ALLEN|Exercise All Questions|30 Videos
  • ELECTROCHEMISTRY

    ALLEN|Exercise EXERCISE -05 [B]|38 Videos

Similar Questions

Explore conceptually related problems

For the water gas reaction, C(s) +H_(2)O(g) hArr CO(g)+H_(2)(g) the standard Gobbs free energy of reaction (at 1000K) is -8.1 kJ mol^(-1) . Calculate its equilibrium constant.

Write the equilibrium constant of the reaction C(s)+H_(2)O(g)hArrCO(g)+H_(2)(g)

Knowledge Check

  • For the reaction H_(2)(g) + I_(2) (g) hArr 2HI (g), the standard free energy is DeltaG^(Theta) gt 0. the equilibrium constant (k) would be. (A)K = 0 (B)K > 1 (C)K = 1 (D)K < 1

    A
    `K=0`
    B
    `Kgt1`
    C
    `K=1`
    D
    `Klt1`
  • Similar Questions

    Explore conceptually related problems

    For the reaction at 298K: A_((g)) +B_((g)) hArr C_((g)) + D_((g)) Delta H^(@) + 29.8kcal and Delta S^(@) = 100cal K^(-1) . Find the value of equilibrium constant.

    At a certain temperature , the equilibrium constant (K_(c)) is 4//9 for the reaction : CO(g)+H_(2)O(g) hArr CO_(2)(g)+H_(2)(g) If we take 10 mole of each of the four gases in a one - litre container, what would be the equilibrium mole percent of H_(2)(g) ?

    Equilibrium constant for the reaction: H_(2)(g) +I_(2) (g) hArr 2HI(g) is K_(c) = 50 at 25^(@)C The standard Gibbs free enegry change for the reaction will be:

    If the equilibrium constant of a reaction is 2×10^3 at 25°C then the standard Gibbs free energy change for the reaction will be

    For the reaction, C_(7)H_(8)(I) + 9O_(2)(g) rarr 7 CO_(2)(g) + 4H_(2)O(I) , the calculated heat of reaction is 232 kJ mol^(-1) and observed heat of reaction is 50.4 kJ mol^(-1) , then the resonance energy is

    Greenhouse gas CO_(2) can be converted to CO(g) by the following reaction CO_(2)(g)+H_(2)(g) rarr CO+H_(2)O(g) , termed as water gas reaction. Calculate DeltaG for the reaction at 1000K (DeltaH_(1000K)=35040 J "mol"^(-1) DeltaS_(1000K) =32.11 J "mol"^(-1)K^(1)) .

    For an equilibrium reaction, if the value of standard Gibb's free energy, AG° is zero, then the value of equilibrium constant, K will be equal to