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Acetylene on heating in the presence of ...

Acetylene on heating in the presence of red hot Fe tube gives :

A

Benzene

B

Cyclooctatetraene

C

naphthalene

D

Anthracene

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The correct Answer is:
To solve the question regarding what acetylene (ethyne) produces when heated in the presence of a red hot iron tube, we can follow these steps: ### Step 1: Identify the Structure of Acetylene Acetylene, also known as ethyne, has the chemical formula C₂H₂. Its structure can be represented as H-C≡C-H, where there is a triple bond between the two carbon atoms. **Hint:** Remember that acetylene is a simple alkyne with a triple bond between two carbon atoms. ### Step 2: Understand the Reaction Conditions The question specifies that acetylene is heated in the presence of a red hot iron tube. The temperature is typically around 873 Kelvin. Under these conditions, acetylene can undergo a reaction known as polymerization. **Hint:** Heating acetylene can lead to various reactions, including polymerization, especially in the presence of a catalyst like iron. ### Step 3: Describe the Polymerization Process When acetylene is heated, it can trimerize, meaning three molecules of acetylene can combine to form a larger molecule. In this case, the trimerization of acetylene leads to the formation of a cyclic structure. **Hint:** Trimerization involves the combination of three monomer units to form a polymer. ### Step 4: Determine the Product of the Reaction The trimerization of acetylene results in the formation of benzene (C₆H₆). The reaction can be summarized as three acetylene molecules combining to form one benzene molecule. **Hint:** Benzene is a cyclic compound with alternating double bonds, which can be formed from the trimerization of acetylene. ### Step 5: Write the Overall Reaction The overall reaction can be represented as: \[ 3 \text{C}_2\text{H}_2 \xrightarrow{\text{red hot Fe}} \text{C}_6\text{H}_6 \] This indicates that three molecules of acetylene yield one molecule of benzene when heated in the presence of red hot iron. **Hint:** Always balance the chemical equation to ensure that the number of atoms on both sides is equal. ### Final Answer When acetylene is heated in the presence of a red hot iron tube, it gives benzene. ---
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ALLEN-CHEMISTRY AT A GLANCE-ORGANIC CHEMISTRY
  1. Reagent x can be

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  2. Which one of the following compounds will give white precipitate wit...

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  3. Acetylene on heating in the presence of red hot Fe tube gives :

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  4. Which among the following alkenes will be most stable :

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  5. Which among the following compounds will give Wurtz reaction ?

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  7. One of the following which does not observe the anti-Markovnikoff's ad...

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  8. Propyne and propene can be distinguished by conc. H2SO4 Br2 in "CCl"...

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  9. which of these will not react with acetylene ?

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  10. What happens when acetylene is treated with hypochlorous acid

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  11. Complete the following reaction

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  12. CH(3)-underset(CH(3))underset(|)overset(CH(3))overset(|)C-CH=CH-CH(3)o...

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  13. During debromination of meso-dibromobutane, the major compound formed ...

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  14. Which is maximum reactive towords acid catalysed dehydration :

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  15. Which gives ketonic group after hydroboration oxidation :

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  16. Complete the following reaction

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  17. on oxymercuration demercuaration produces the major product

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  18. How many chiral compounds are possible on monochlorination of 2-methyl...

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