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CH(3)CH(2)CH(CHO)CH(2)CH(3) and CH(3)CH...

`CH_(3)CH_(2)CH(CHO)CH_(2)CH_(3) and`
`CH_(3)CH(CHO) CH_(2)CH_(2)CH_(3)` are :-

A

Chain isomer

B

Position isomer

C

Metamerism

D

Functional isomer

Text Solution

AI Generated Solution

The correct Answer is:
To determine the type of isomerism exhibited by the compounds \( CH_3CH_2CH(CHO)CH_2CH_3 \) and \( CH_3CH(CHO)CH_2CH_2CH_3 \), we will follow these steps: ### Step 1: Identify the Functional Groups Both compounds contain the aldehyde functional group (-CHO). This indicates that they are both aldehydes. ### Step 2: Analyze the Molecular Formula We need to check if both compounds have the same molecular formula. - For \( CH_3CH_2CH(CHO)CH_2CH_3 \): - Count the carbon (C), hydrogen (H), and oxygen (O) atoms: - C: 5 - H: 10 - O: 1 - Molecular formula: \( C_5H_{10}O \) - For \( CH_3CH(CHO)CH_2CH_2CH_3 \): - Count the carbon (C), hydrogen (H), and oxygen (O) atoms: - C: 5 - H: 10 - O: 1 - Molecular formula: \( C_5H_{10}O \) Both compounds have the same molecular formula \( C_5H_{10}O \). ### Step 3: Determine the Type of Isomerism Now we need to determine the type of isomerism: - **Functional Isomerism**: This occurs when compounds have the same molecular formula but different functional groups. Since both compounds are aldehydes, they do not exhibit functional isomerism. - **Position Isomerism**: This occurs when the functional group is in different positions on the carbon chain. In this case, both compounds have the -CHO group, but they are located at different positions in the carbon chain. - **Chain Isomerism**: This occurs when the carbon skeleton differs in arrangement (i.e., the branching of the carbon chain). ### Step 4: Conclusion Given that both compounds are aldehydes and have the same molecular formula but differ in the arrangement of the carbon skeleton, they are classified as **chain isomers**. ### Final Answer The compounds \( CH_3CH_2CH(CHO)CH_2CH_3 \) and \( CH_3CH(CHO)CH_2CH_2CH_3 \) are **chain isomers**. ---
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Name the functional groups present in the following compounds. (a) CH_(3)COCH_(2)CH_(2)CH_(2)CH_(3) , (b) CH_(3)CH_(2)CH_(2)COOH (c ) CH_(3)CH_(2)CH_(2)CH_(2)CHO , (d) CH_(3)CH_(2)OH

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Knowledge Check

  • Assertion : The boiling points of given compounds follow the order : CH_(3)CH_(2)CH_(2)CHO ~~CH_(3)CH_(2)CH_(2)CH_(2)CH_(3) lt CH_(3)CH_(2)CH_(2)CH_(2)OH ~~ H_(5)C_(2)OC_(2)H_(5) Reason : Boiling point depends upon molecualr mass only.

    A
    If both assertion and reason are true and reason is the correct explanation of assertion.
    B
    If both assertion and reason are true but reason is not the correct explanation of assertion.
    C
    If assertion is true but reason is false.
    D
    If both assertion and reason are false.
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