Home
Class 12
CHEMISTRY
Oxidation state of nitrogen is incorrect...

Oxidation state of nitrogen is incorrectly given for:

A

`{:("Compound","Oxidation State"),([Co(NH_(3))_(5)Cl]Cl_(2),-3):}`

B

`{:("Compound","Oxidation State"),(NH_(2)OH,-1):}`

C

`{:("Compound","Oxidation State"),((N_(2)H_(5))_(2)SO_(4),+2):}`

D

`{:("Compound","Oxidation State"),(Mg_(3)N_(2),-3):}`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the oxidation state of nitrogen in various compounds, we will analyze each option step by step. ### Step 1: Analyze the first compound, Co(NH3)5Cl2 1. **Identify the overall charge**: The complex has a counter ion of Cl2, which indicates that the overall charge of the complex is +2. 2. **Set up the equation**: Let the oxidation state of cobalt (Co) be \(X\). The ammonia (NH3) is a neutral ligand, contributing 0 to the charge. The chlorine (Cl) contributes -1 for each Cl atom. \[ X + 5(0) + (-1) = +2 \] Simplifying this gives: \[ X - 1 = +2 \implies X = +3 \] 3. **Conclusion**: The oxidation state of cobalt is +3, which is correctly given. ### Step 2: Analyze the second compound, NH2OH (Hydroxylamine) 1. **Identify the overall charge**: NH2OH is a neutral molecule, so the overall oxidation state must be 0. 2. **Set up the equation**: Let the oxidation state of nitrogen be \(X\). \[ X + 3(+1) + (-2) = 0 \] Simplifying this gives: \[ X + 3 - 2 = 0 \implies X + 1 = 0 \implies X = -1 \] 3. **Conclusion**: The oxidation state of nitrogen is -1, which is correctly given. ### Step 3: Analyze the third compound, N2H5SO4 1. **Identify the overall charge**: N2H5SO4 is a neutral molecule, so the overall oxidation state must be 0. 2. **Set up the equation**: Let the oxidation state of nitrogen be \(X\). \[ 2X + 5(+1) + (-2) = 0 \] Simplifying this gives: \[ 2X + 5 - 2 = 0 \implies 2X + 3 = 0 \implies 2X = -3 \implies X = -\frac{3}{2} \] However, since we have 2 nitrogen atoms, we can also express this as: \[ 4X + 10 - 2 = 0 \implies 4X + 8 = 0 \implies 4X = -8 \implies X = -2 \] 3. **Conclusion**: The oxidation state of nitrogen is -2, but it is incorrectly given as +2. ### Step 4: Analyze the fourth compound, Mg3N2 1. **Identify the overall charge**: Mg3N2 is a neutral compound, so the overall oxidation state must be 0. 2. **Set up the equation**: Let the oxidation state of nitrogen be \(X\). \[ 3(+2) + 2X = 0 \] Simplifying this gives: \[ 6 + 2X = 0 \implies 2X = -6 \implies X = -3 \] 3. **Conclusion**: The oxidation state of nitrogen is -3, which is correctly given. ### Final Conclusion: The oxidation state of nitrogen is incorrectly given for the compound **N2H5SO4**, where it should be -2 but is incorrectly stated as +2.
Promotional Banner

Topper's Solved these Questions

  • REDOX REACTIONS

    ALLEN|Exercise EXERICSE - 2|50 Videos
  • REDOX REACTIONS

    ALLEN|Exercise EXERICSE - 3|30 Videos
  • REDOX REACTIONS

    ALLEN|Exercise Questions|24 Videos
  • Redox Reaction

    ALLEN|Exercise All Questions|19 Videos
  • s-Block element

    ALLEN|Exercise All Questions|14 Videos

Similar Questions

Explore conceptually related problems

The oxidation state of nitrogen is correctly given for

The oxidation state of nitrogen is highest in

Oxidation state of nitrogen in H-N equiv C is

When zinc reacts with very dilute HNO_(3) , the oxidation state of nitrogen changes from:

The oxidation state of nitrogen varies from:

Oxidation states in nitrogen can range from

-1//3 oxidation state of nitrogen will be obtained in case of :

Arrange in the increasing order of oxidation state of nitrogen for following nitrogen oxides N_(2)O, NO_(2), NO, N_(2)O_(3)

One mole of N_(2)H_(4) loses ten moles of electrons to form a new compound A . Assuming that all the nitrogen appears in the new compound, what is the oxidation state of nitrogen in A ? (There is no change in the oxidation state of hydrogen.)

What is the difference in oxidation state of nitrogen in between hydroxyl amine (NH_(2)OH) and hydrazine (N_(2)H_(4)) ?

ALLEN-REDOX REACTIONS-Exercise - 1
  1. Which of the following shows highest oxidation number of combined stat...

    Text Solution

    |

  2. Oxidation number of sodium is sodium amalgam is :

    Text Solution

    |

  3. Oxidation state of nitrogen is incorrectly given for:

    Text Solution

    |

  4. The oxidation number of C in HNC is

    Text Solution

    |

  5. The oxidation number of Fe in Fe(0.94)O is

    Text Solution

    |

  6. Oxidation number of carbon in carbon suboxide (C(3)O(2)) is :

    Text Solution

    |

  7. Oxidation number of sulphur in Na(2)S(2)O(3) is

    Text Solution

    |

  8. Two oxidation states for chlorine are found in the compound :

    Text Solution

    |

  9. {:(,"Compounds",,"O.N."),((A),KMn^(**)O(4),(1),+4),((B),Ni^(**)(CO)(4)...

    Text Solution

    |

  10. -1//3 oxidation state of nitrogen will be obtained in case of :

    Text Solution

    |

  11. Find the oxidation number of Fe in Fe(3)O(4)

    Text Solution

    |

  12. Compound YBa(2)Cu(3)O(7) is a super conductor The O.N. of the copper i...

    Text Solution

    |

  13. Which one of the following is a redox reaction ?

    Text Solution

    |

  14. Which of the following is not a redox reaction ?

    Text Solution

    |

  15. In the context of the reaction, 4Fe+3O(2)rarr4Fe^(3+)+6O^(2-) , whic...

    Text Solution

    |

  16. In the reaction :Cl(2)+OH^(-)rarrCl^(-)+ClO(4)^(-)+H(2)O

    Text Solution

    |

  17. Which is a redox reaction :

    Text Solution

    |

  18. Which of the following examples does not represent disproportionation ...

    Text Solution

    |

  19. The decomposition of KClO(3) to KCl and O(2) on heating is an example ...

    Text Solution

    |

  20. Which of the following changes represent a disproportionation reaction...

    Text Solution

    |