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Assertion : In the reaction, (1)/(2)O(2)...

Assertion : In the reaction, `(1)/(2)O_(2)+F_(2)rarrOF_(2)` Fluorine is oxidant.
Reason :- Fluorine cannot show positive oxidation state.

A

If both Assertion & Reason are True & the Reason is a correct explanation of the Assertion.

B

If both Assertion & Reason are True but Reason is not a correct explanation of the Assertion.

C

If Assertion is True but the Reason is False.

D

If both Assertion & Reason are False.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Understand the Assertion The assertion states that in the reaction \( \frac{1}{2} O_2 + F_2 \rightarrow OF_2 \), fluorine acts as an oxidant. - In this reaction, oxygen (O) is reacting with fluorine (F) to form oxygen difluoride (OF2). - To determine whether fluorine is an oxidant, we need to look at the oxidation states of the elements involved. ### Step 2: Determine Oxidation States In the compound OF2: - Oxygen typically has an oxidation state of -2. - Fluorine, being the most electronegative element, has an oxidation state of -1 in OF2. Thus, in the reaction: - The oxidation state of O in \( O_2 \) is 0 (elemental form). - The oxidation state of F in \( F_2 \) is also 0 (elemental form). ### Step 3: Identify Changes in Oxidation States - Oxygen goes from 0 in \( O_2 \) to +2 in \( OF_2 \). - Fluorine goes from 0 in \( F_2 \) to -1 in \( OF_2 \). This indicates that: - Oxygen is being oxidized (its oxidation state increases). - Fluorine is being reduced (its oxidation state decreases). Since fluorine causes the oxidation of oxygen, it acts as an oxidizing agent (or oxidant). ### Step 4: Analyze the Reason The reason states that fluorine cannot show a positive oxidation state. - This statement is true. Fluorine is the most electronegative element and typically exhibits a -1 oxidation state in compounds. - However, this fact does not explain why fluorine is an oxidant in the given reaction. ### Conclusion - The assertion is correct: Fluorine is indeed an oxidant in the reaction. - The reason is also correct: Fluorine cannot show a positive oxidation state. - However, the reason does not correctly explain the assertion. Thus, the answer is: **Option B: Both assertion and reason are correct, but the reason is not the correct explanation of the assertion.**
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Knowledge Check

  • Assertion : The oxidation number of fluorine in all its compounds is always -1 Reason : Fluorine is a highly reactive element .

    A
    If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.
    B
    If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.
    C
    If Assertion is CORRECT but Reason is INCORRECT.
    D
    If Assertion is INCORRECT but Reason is CORRECT.
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