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Assertion :- O.N. of carbon in H-C-=N is...

Assertion :- O.N. of carbon in `H-C-=N` is `+4`.
Reason :- Carbon always shows an O.N of +4.

A

If both Assertion & Reason are True & the Reason is a correct explanation of the Assertion.

B

If both Assertion & Reason are True but Reason is not a correct explanation of the Assertion.

C

If Assertion is True but the Reason is False.

D

If both Assertion & Reason are False.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Analyze the Assertion The assertion states that the oxidation number (O.N.) of carbon in the compound H-C≡N (hydrogen cyanide) is +4. 1. **Identify the oxidation states of other elements:** - Hydrogen (H) typically has an oxidation number of +1. - Nitrogen (N) in this case, being part of a triple bond with carbon, will have an oxidation number of -3. 2. **Set up the equation:** - Let the oxidation number of carbon be represented as \( x \). - The overall charge of the molecule is 0, so we can write the equation: \[ 1 \times (+1) + 1 \times (x) + 1 \times (-3) = 0 \] 3. **Simplify the equation:** \[ +1 + x - 3 = 0 \] \[ x - 2 = 0 \] \[ x = +2 \] Thus, the oxidation number of carbon in H-C≡N is +2, not +4. Therefore, the assertion is **false**. ### Step 2: Analyze the Reason The reason states that carbon always shows an oxidation number of +4. 1. **Understand carbon's oxidation states:** - Carbon can exhibit multiple oxidation states, ranging from -4 to +4. - For example, in methane (CH₄), carbon has an oxidation state of -4, and in carbon dioxide (CO₂), it has an oxidation state of +4. 2. **Conclusion about the reason:** - Since carbon can have oxidation states other than +4, the statement that carbon always shows an oxidation number of +4 is also **false**. ### Final Conclusion Both the assertion and the reason are false. Therefore, the correct answer is that both statements are incorrect. ### Summary of the Solution - The assertion is false because the oxidation number of carbon in H-C≡N is +2, not +4. - The reason is false because carbon does not always have an oxidation number of +4; it can vary between -4 and +4.
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