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Cl(2)(g)rarr2Cl(g), In this process valu...

`Cl_(2)(g)rarr2Cl(g)`, In this process value of `Delta H` will be -

A

Positive

B

Negative

C

Zero

D

Nothing can be predicted

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AI Generated Solution

The correct Answer is:
To determine the value of ΔH for the reaction \( \text{Cl}_2(g) \rightarrow 2\text{Cl}(g) \), we need to analyze the process in terms of bond energies and whether energy is absorbed or released. ### Step-by-Step Solution: 1. **Identify the Reaction**: The reaction given is \( \text{Cl}_2(g) \rightarrow 2\text{Cl}(g) \). This indicates that one molecule of chlorine gas (Cl2) dissociates into two chlorine atoms (Cl). 2. **Understand Bond Energy**: In the diatomic chlorine molecule (Cl2), there is a strong Cl-Cl bond. To break this bond and form two separate chlorine atoms, energy must be supplied to overcome the bond energy. 3. **Determine Energy Change (ΔH)**: - When a bond is broken, energy is absorbed. Therefore, the process of breaking the Cl-Cl bond requires energy input. - Since energy is absorbed in this reaction, the change in enthalpy (ΔH) for the reaction will be positive. 4. **Conclusion**: Based on the analysis, since energy is absorbed to break the bond in Cl2, the value of ΔH for the reaction \( \text{Cl}_2(g) \rightarrow 2\text{Cl}(g) \) is positive. ### Final Answer: The value of ΔH will be positive.
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ALLEN-THERMODYNAMICS -EXERCISE -3
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  2. The enthalpy change for the reaction 2C("graphite")+3H(2)(g)rarrC(2)H(...

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  3. Cl(2)(g)rarr2Cl(g), In this process value of Delta H will be -

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  4. The magnitude of heat of solution ….. On addition of solvent to soluti...

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  5. If H(2)(g) rarr 2H(g) " "DeltaH = 104 kcals Then heat of atomizat...

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  6. The heat of combustion of yellow phoshphorus and red phosphorus are -9...

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  7. For the change,C("diamond") rarr C("graphite"), Delta H = -1.89 kJ , i...

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  8. 2CO((g))+O(2(g))rarr 2CO(2(g))+X KJ In the above equation X KJ refers ...

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  9. Which of the following reactions represents Delta H (hydration) :-

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  10. Delta H for the reaction, I((g))+I((g))rarr I(2(g)) will be :-

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  11. Given that {:(A(s) rarr A(I)," ",Delta H = x),(A(I) rarr A(g)," ...

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  12. The enthalpy change of a reaction does not depend on

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  13. Form the thermochemical reactions. C(graphite) +1//2 O(2)(g) to CO(g...

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  14. If H(2)+1//2O(2)rarr H(2)O , Delta =-68.39 Kcal K+H(2)O+ "water" rar...

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  15. Given C(s)+O(2)(g)rarr CO(2)(g)+94.2 Kcal H(2)(g)+2O(2)(g)rarr CO(2)...

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  16. From the following data, the heat of formation of Ca(OH)(2)(s) at 18^(...

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  17. If H(2)(g) + Cl(2)(g) rarr 2HCl, Delta H^(@) = -44 kcal" "…..(i) ...

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  18. In the reaction : S+3//2O(2) rarr SO(3)+"2x kcal" and SO(2) +1//2O(2) ...

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  19. If S+O(2)toSO(2),DeltaH=-298.2 " kJ" " mole"^(-1) SO(2)+(1)/(2)O(2)t...

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  20. Givecn that : Zn+1//2O(2)rarr ZnO+84000 cal ……………1 Hg+1//2O(2)rarr...

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