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Let speed of sound waves in hydrogen gas...

Let speed of sound waves in hydrogen gas at room temperature is `v_(0)`. What will be the speed of sound waves in a room which contains an equimolar mixture of hydrogen and 'He' at same temperature :-

A

`sqrt((5)/(7))v_(0)`

B

`sqrt((7)/(5))v_(0)`

C

`sqrt((2)/(5))v_(0)`

D

None

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The correct Answer is:
To find the speed of sound waves in an equimolar mixture of hydrogen and helium at room temperature, we can follow these steps: ### Step 1: Understand the formula for the speed of sound The speed of sound in a gas is given by the formula: \[ v = \sqrt{\frac{\gamma RT}{M}} \] where: - \( v \) = speed of sound - \( \gamma \) = adiabatic index (ratio of specific heats) - \( R \) = universal gas constant - \( T \) = absolute temperature - \( M \) = molar mass of the gas ### Step 2: Calculate speed of sound in hydrogen For hydrogen (\( H_2 \)): - It is a diatomic gas, thus \( \gamma_H = \frac{C_p}{C_v} = \frac{7}{5} \). - The molar mass \( M_H \) of hydrogen is \( 2 \, \text{g/mol} \). Using the formula: \[ v_0 = \sqrt{\frac{\gamma_H RT}{M_H}} = \sqrt{\frac{\frac{7}{5}RT}{2}} \] ### Step 3: Calculate speed of sound in helium For helium (\( He \)): - It is a monoatomic gas, thus \( \gamma_{He} = \frac{C_p}{C_v} = \frac{5}{3} \). - The molar mass \( M_{He} \) of helium is \( 4 \, \text{g/mol} \). Using the formula: \[ v_{He} = \sqrt{\frac{\gamma_{He} RT}{M_{He}}} = \sqrt{\frac{\frac{5}{3}RT}{4}} \] ### Step 4: Calculate the effective \( \gamma \) and \( M \) for the mixture Since we have an equimolar mixture of hydrogen and helium, we can find the effective \( \gamma \) and \( M \) for the mixture. 1. **Effective \( C_p \) and \( C_v \)**: - For hydrogen: \( C_{p,H} = \frac{7R}{2} \) and \( C_{v,H} = \frac{5R}{2} \) - For helium: \( C_{p,He} = \frac{5R}{2} \) and \( C_{v,He} = \frac{3R}{2} \) Using the formula for \( \gamma \) of the mixture: \[ \gamma_{mix} = \frac{N_1C_{p,H} + N_2C_{p,He}}{N_1C_{v,H} + N_2C_{v,He}} \] Since \( N_1 = N_2 = 1 \): \[ \gamma_{mix} = \frac{\frac{7R}{2} + \frac{5R}{2}}{\frac{5R}{2} + \frac{3R}{2}} = \frac{12R/2}{8R/2} = \frac{12}{8} = \frac{3}{2} \] 2. **Effective molar mass \( M_{mix} \)**: \[ M_{mix} = \frac{M_H + M_{He}}{2} = \frac{2 + 4}{2} = 3 \, \text{g/mol} \] ### Step 5: Calculate the speed of sound in the mixture Using the effective values: \[ v_{mix} = \sqrt{\frac{\gamma_{mix} RT}{M_{mix}}} = \sqrt{\frac{\frac{3}{2}RT}{3}} = \sqrt{\frac{RT}{2}} \] ### Step 6: Relate \( v_{mix} \) to \( v_0 \) Now, we can relate \( v_{mix} \) to \( v_0 \): \[ v_{mix} = \sqrt{\frac{RT}{2}} = \sqrt{\frac{7}{10} \cdot \frac{RT}{2}} = \sqrt{\frac{7}{10}} \cdot v_0 \] ### Final Result Thus, the speed of sound in the equimolar mixture of hydrogen and helium is: \[ v_{mix} = \sqrt{\frac{5}{7}} v_0 \]
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