Home
Class 12
CHEMISTRY
Electron affinity of the elements or ion...

Electron affinity of the elements or ions is correctly shown in

A

`SgtO^(-)`

B

`OgtS^(-)`

C

`O^(-)gtS^(-)`

D

`N^(-)gtS`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the electron affinity of elements or ions, we will analyze the concept of electron affinity and compare the electron affinities of specific elements. ### Step-by-Step Solution: 1. **Understand Electron Affinity**: - Electron affinity is defined as the amount of energy released when an electron is added to a gaseous atom. It is an exothermic process, meaning that energy is released, and thus the change in enthalpy (ΔH) is negative. **Hint**: Remember that electron affinity is related to how easily an atom can accept an electron. 2. **Analyze the Elements**: - We will consider the electron affinities of sulfur (S), oxygen (O), and nitrogen (N). - Sulfur has an electronic configuration of [Ne] 3s² 3p⁴. - Oxygen has an electronic configuration of [He] 2s² 2p⁴. - Nitrogen has an electronic configuration of [He] 2s² 2p³. **Hint**: Write down the electronic configurations to visualize the electron arrangements. 3. **Compare Electron Affinities**: - **Oxygen**: When an electron is added to oxygen, it goes from 2p⁴ to 2p⁵. There is significant intra-electronic repulsion due to the added electron being placed in the same p orbital, which makes it less favorable for oxygen to gain an electron. - **Sulfur**: In sulfur, when an electron is added, it goes from 3p⁴ to 3p⁵. The presence of empty d orbitals allows for better accommodation of the added electron, resulting in a higher electron affinity compared to oxygen. - **Nitrogen**: For nitrogen, adding an electron would lead to an increase in intra-electronic repulsion as well, since it would go from 2p³ to 2p⁴. Thus, nitrogen has a lower electron affinity than sulfur. **Hint**: Consider the size of the atoms and the presence of empty orbitals when comparing their ability to accept electrons. 4. **Conclusion**: - Based on the analysis, sulfur has a greater electron affinity than oxygen and nitrogen. Therefore, the correct statement regarding electron affinity is that sulfur has a higher electron affinity than O⁻ (the oxide ion) due to its larger size and the absence of significant intra-electronic repulsion. **Hint**: Summarize your findings by comparing the electron affinities of the elements directly. ### Final Answer: The electron affinity of sulfur is greater than that of oxygen and nitrogen, making option A the correct choice.

To solve the question regarding the electron affinity of elements or ions, we will analyze the concept of electron affinity and compare the electron affinities of specific elements. ### Step-by-Step Solution: 1. **Understand Electron Affinity**: - Electron affinity is defined as the amount of energy released when an electron is added to a gaseous atom. It is an exothermic process, meaning that energy is released, and thus the change in enthalpy (ΔH) is negative. **Hint**: Remember that electron affinity is related to how easily an atom can accept an electron. ...
Doubtnut Promotions Banner Mobile Dark
|

Similar Questions

Explore conceptually related problems

Electron affinity is the

Electron affinity of the elements or ions shown correctly?

Knowledge Check

  • Electron affinity is maximum in:

    A
    Alkali metals
    B
    Alkaline earth metals
    C
    Halogens
    D
    Inert gases
  • Similar Questions

    Explore conceptually related problems

    Electron affinity is the :

    Order of Electron affinity of the elements or ions shown correctly?

    Order of Electron affinity of the elements or ions shown correctly?

    The correct order of electron affinity of the elements of oxygen family in the periodic table is

    Electron affinity of noble gas elements is zero.Explain.

    Assertion: First electron affinity of all elements is positive. Reason: Successive electron affinity of all elements is negative.

    The electron affinity of nitrogen is zero.