Home
Class 12
CHEMISTRY
By using valence bond theory discuss the...

By using valence bond theory discuss the geometry aud magnetic nature of `[Cr(NH_3)_6]^(3+)` ion.

Text Solution

Verified by Experts

The hybridisation and formation of `[Cr(NH_3)_6]^(3+)` ion is shhown as below :

The ion `Cr^(3+)` has two vacant d- orbitals. These orbitals. These orbitals get hybridised with one 4s and three 4p-orbitals resulting in `d^2 sp^3` hybridisation. Now the six vacant `d^2sp^3` hybrid orbitals are occupied by has octahedral geometry. Since there are three unpaired d - electrons, it is paramagnetic in nature.
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • CO-ORDINATION COMPOUNDS

    OMEGA PUBLICATION|Exercise MULTIPLE CHOICE QUESTIONS |38 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    OMEGA PUBLICATION|Exercise MULTIPLE CHOICE QUESTIONS (MCQs)|20 Videos
  • ELECTROCHEMISTRY

    OMEGA PUBLICATION|Exercise MULTIPLE CHOCIE QUESTION |46 Videos

Similar Questions

Explore conceptually related problems

Using valence bond theory predict the geometry and magnetic behaviour of [Pt(CN)_4]^(2-) .

On the basis of valence bond theory explain the structure and magnetic nature of [Fe(H_2O)_6]^(3+) complex ion.

Onthe basis of valence bond theory explain the structure and magnetic nature of [Fe(CN)_6]^(3_) complex ion.

Using valence bond theory of complexes, explain the geometry and diamagnetic nature of the ion [Cr(NH_3)_6]^(3+) . Given the atomic number of Cr=24 .

Using valence bond theory of complexes, explain the geometry and diamagnetic nature of the ion [Cr(NH_3)_6]^(3+) . Given the atomic number of Cr=24 .

Using valence bond theory of complexes, explain the geometry and diamagnetic nature of the ion [Cr(NH_3)_6]^(3+) . Given the atomic number of Cr = 241.

Using valence bond theory explain the geometry and magnetic behaviour of pentacarbonyl iron (0).

Discuss structure of [Co(NH_3)_6]^(3+) complex ion.

On the basis of valence bond theory explain the shape and magnetic character of K_4[Fe(CN)_6] or Fe(CN)_6]^(4-) ion.

Based on VBT, explain geometry and magnetic behavior of [Fe(CN)_6]^(-4) ion.