Home
Class 12
CHEMISTRY
Why Phenols are more acidic than Alcohol...

Why Phenols are more acidic than Alcohol ?

Text Solution

Verified by Experts

Phenol are more acidic than alcohol :
The greater acidic character of phenols as compared to alcohols can be explained on the basis of resonance. Phenol is a Resonance hybrid of the following structures :

It is clear that three structure of phenol (III, IV and V) having positive charge on oxygen of - OH group. This oxygen attracts the electron pair of O-H bond strongly towards itself and weakens the O-H bond and therefore, facilitates the release of `H^(+)` ion. So phenol is more acidic . On the other hand, in case of alcohols, neither the alcohol nor the alkoxide ion is stabilized by resonance.

No resonance stabilization for alcohol or alkoxide ion.
Thus, phenol are more acidic than alcohols. However, phenols are less acidic than carboxylic acids which is supported by their dissociation constant values.
Promotional Banner

Topper's Solved these Questions

  • SOLVED MODEL TEST PAPER-1

    ACCURATE PUBLICATION|Exercise SECTION D|14 Videos
  • SOLVED MODEL TEST PAPER-1

    ACCURATE PUBLICATION|Exercise SECTION B|17 Videos
  • SOLVED SAMPLE PAPER, MARCH - 2021

    ACCURATE PUBLICATION|Exercise SECTION -D |16 Videos
  • SOLVED MODEL TEST PAPER-2

    ACCURATE PUBLICATION|Exercise SECTION D|11 Videos

Similar Questions

Explore conceptually related problems

Water is more acidic than alcohol

Why are amines less acidic than alcohols ?

Orthonitrophenol and paranitrophenol are more acidic than phenols. Give reasons.

Why carboxylic acids are more acidic than Phenols ?