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State and explain the term diastereoisom...

State and explain the term diastereoisomers and mesomers.

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Diastereoisomers : Stereoisomers which are not related to each other as mirror images are called diastereomers.
Mesomers : Optical isomers which are optically inactive due to the presence of plane of symmtry i.e., do not rotate the plane of polarised light are called mesomers. For example , in case of 2, 3-dichlorobutane the pair (1) and (II) represents a pair of enantiomers, pair (I) and (III) or pair (II) and (III) represent pairs of diastereoisomers. Here (III) is a meso compound and is optically inactive. It is achiral. As all these thrce isomers behave differently towards the polarised light, they are termed as optical isomers.
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BETTER CHOICE PUBLICATION-HALOALKANES AND HALOARENES-QUESTIONS
  1. Give different Enantiomers of 2 chlorobutane.

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  2. Give different Enantiomers of 3-methyl hexane.

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  3. State and explain the term diastereoisomers and mesomers.

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  4. What is racemisation ?

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  5. Define asymmetric synthesis.

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  6. Point out the difference between : Chirality and chiral centre (or c...

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  7. Point out the difference between : Enantiomers and diastereomers.

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  8. Differentiate between recemic mixture and meso compound .

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  9. Define inversion.

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  10. Define retention.

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  11. The p-isomer of dichlorobenzene has higher melting point than O-and M-...

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  12. The p-isomer of dichlorobenzene has higher melting point than O-and M-...

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  13. Give reasons : Boiling point of alkyl bromide is higher than alkyl c...

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  14. Give reasons : Alkyl halides are better solvents than aryl halides.

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  15. Give reasons : Haloalkanes used as solvents in industry are chloro ...

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  16. What are ambident uncleophiles ? Explain with an example.

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  17. Alkyl Chloride is more reactive than chlorobenzene towards nucleophili...

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  18. With the help of polarity of the carbon halogen bond show that aryl ha...

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  19. Why are haloarenes more stable than haloalkanes ?

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  20. Why do alkyi haldies undergo hydrolysis more readily than aryl halides...

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