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Explain why [Ti (H2O)6]^(3+) is violet w...

Explain why `[Ti (H_2O)_6]^(3+)` is violet while `[Ti (H_2O)_6]^(4+)` is colourless.

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`Ti` has electrónic configuration : `[Ar]^(18) 3d^2 4s^2`

With one electron in 3d-Subshell in `Ti^(3+)`, d-d transitions are possible and hence it is coloured with electron 3d-subshell

In `Ti^(4+)`, d-d transitions are not possible and hence it is colourless.
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ACCURATE PUBLICATION-D & F BLOCK ELEMENTS -2 OR 5 MARKS QUESTIONS
  1. [Ti (H2O)6]^(3+) is coloured while [Sc(H2O)6]^(3+) is colourless. Expl...

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  2. Explain why TiCl3 is coloured but TiCl4 is colourless ?

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  3. Explain why [Ti (H2O)6]^(3+) is violet while [Ti (H2O)6]^(4+) is colou...

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  4. Why Cd^(2+) salts are white ? Cd=48

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  5. Which of the two is paramagnetic V(IV) or V(V) and why ?

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  6. Why does Mn(II) shows maximum paramagnetic character among the dival...

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  7. Name the elements represented by following symbols : Hg , Pb , Au , Ag...

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  8. What is atomicity ? Explain with two examples.

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  9. What is the atomicity of the following : oxygen

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  10. Explain why Cu(I) is diamagnetic while Cu(II) is paramagnetic in natur...

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  11. Transition metals have high melting points and boiling points. Why?

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  12. What is the atomicity of the following : ozone

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  13. What is the atomicity of the following : neon

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  14. What is the atomicity of the following : phosphorous

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  15. What is the atomicity of the following : sulphur

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  16. What is the atomicity of the following : sodium

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  17. What are lanthanoids ?

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  18. Why are Lanthanides called inner transition metals.

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  19. What are different oxidation states exhibited by lanthanoids ?

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  20. What is lanthanoid contraction ?

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