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Equal amount of an RCl(C4H9Cl) is reacte...

Equal amount of an `RCl(C_4H_9Cl)` is reacted at the same temperature with equal volume of 0.2 Mand 0.4M. solution of KOH, respectively, in two separate experiments. The time taken for the reaction of 50% of `(C_4H_9Cl)` was found to be same, the alkyl halide is:

A

B

C

D

Text Solution

Verified by Experts

The correct Answer is:
B

Hydrolysis of `3^@` RX is independent of nucleophilic concentration (`SN^(1)` reaction).
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Knowledge Check

  • volume of '0.1 M H, SO_4' solution required to.neutralise '50 ~mL' of '0.2 M NaOH' solution is

    A
    25 mL'
    B
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    C
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  • A 500 mL flask was charged with 1.0 mol of COCl_(2)(g) and heated to some temperature (T) where decomposes partially as , COCl_(2)(g) hArr CO(g) + Cl_(2)(g), K_(c)(T) = 1.5 M Now the above flask is connected to another flask containing some pure chlorine gas at the same temperature and pressure, by a narrow tube of negligible volume. When the equilibrium was restored, the concentration COCl_(2)(g) was found to be 0.694 M. Determine the volume of Cl_(2)(g) flask.

    A
    200 mL
    B
    100 mL
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    120 mL
  • '0.004 M' solution of 'Na_2 SO_4' is isotonic with '0.01 M' solution of glucose at, same temperature. The apparent degree of dissociation of 'Na_2 SO_4' is

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