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For hydrogen gas ,calculate (a) root mea...

For hydrogen gas ,calculate (a) root mean square velocity (b) average velocity and ( c) most probable velocity at `0^(@)C`

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Given : Molar mass , M of `H_(2) = 2.016 g mol^(-1) = 2.016 xx 10^(-3) kg mol^(-1), J = kg m^(2) s^(-2)`
(a) RMS velocity ,`u_("rms") = ((3RT)/(M))^(1//2) = (((3) (8.314 J K^(-1) mol^(-1)) (273.15 K))/(2.016 xx 10^(-3) kg mol^(-1)))^(1//2) = 1.84 xx 10^(3) m s^(-1)`
(b) Average velocity `, u_("avg") = ((8RT)/(pi M))^(1//2) = (((8) (8.314 J K^(-1) mol^(-1)) (273 .15 K))/(3.1416 (2.016 xx 10^(3) kg mol^(-1))))^(1//2) = 1.69 xx 10^(3) ms^(-1)`
(c) Most probable velocity , `u_("mp") = ((2RT)/(M))^(1//2) = (((2) (8.314 J K^(-1) mol^(-1)) (273.15 K))/(2.016 xx 10^(-3) kg mol^(-1)))^(1//2) = 1.50 xx 10^(3) ms^(-1)`
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Knowledge Check

  • Assertion : The root mean square velocity of molecules of a gas having Maxwellian distribution of velocities is higher than their most probable velocity, at any temperature. Reason : A very small number of molecules of a gas which possess very large velocities, increase the root mean square velocity, without affecting the most probable velocity.

    A
    If both Assertion and Reason are true and Reason is the correct explanation of Assertion.
    B
    If both Assertion and Reason are true but Reason is not correct explanation of Assertion.
    C
    If Assertion is true but Reason is false.
    D
    If both Assertion and Reason are false.
  • The ratio among most probable velocity, mean velocity and root mean square velocity is given by

    A
    `1 : 2 : 3`
    B
    `1 : sqrt2 : sqrt3`
    C
    `sqrt2 : sqrt3 : sqrt(8 //pi)`
    D
    `sqrt2 : sqrt(8 // pi) : sqrt3`
  • The ratio among most probable velocity, mean velocity and root mean square velocity is given by

    A
    `1 : 2 : 3`
    B
    `1 : sqrt(2) : sqrt(3)`
    C
    `sqrt(2) : sqrt(3) : sqrt(8"/"pi)`
    D
    `sqrt(2) : sqrt(8"/"pi) : sqrt(3)`
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