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Addition of Br2 to trans-2-butene would ...

Addition of `Br_2` to trans-2-butene would give a product which is

A

achiral

B

racemic

C

meso

D

optically active

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the addition of \( Br_2 \) to trans-2-butene, we will follow these steps: ### Step 1: Draw the structure of trans-2-butene Trans-2-butene has the following structure: \[ \text{CH}_3-CH=CH-CH_3 \] In this structure, the two methyl groups (\( CH_3 \)) are on opposite sides of the double bond, which is characteristic of the trans isomer. ### Step 2: Understand the addition reaction When bromine (\( Br_2 \)) is added to alkenes, it typically undergoes an electrophilic addition reaction. In the case of trans-2-butene, the addition of bromine occurs via an anti-addition mechanism. This means that the bromine atoms will add to opposite sides of the double bond. ### Step 3: Draw the bromonium ion intermediate During the reaction, a bromonium ion is formed as an intermediate. This ion is a cyclic structure where one bromine atom is bonded to one of the carbons in the double bond, creating a positive charge on the other carbon. ### Step 4: Complete the addition of bromine The second bromine atom will then attack the bromonium ion from the opposite side (anti-addition), leading to the formation of a dibromide product. The product formed from trans-2-butene will have the following structure: \[ \text{CH}_3-CHBr-CHBr-CH_3 \] ### Step 5: Analyze the symmetry of the product The final product is a meso compound because it has a plane of symmetry. The two bromine atoms are added to the same side of the molecule, but since the original alkene was trans, the resulting compound will have a mirror plane dividing the molecule into two symmetrical halves. ### Step 6: Conclusion The product of the addition of \( Br_2 \) to trans-2-butene is a meso compound. ### Final Answer The correct answer is that the product is **meso**. ---

To solve the question regarding the addition of \( Br_2 \) to trans-2-butene, we will follow these steps: ### Step 1: Draw the structure of trans-2-butene Trans-2-butene has the following structure: \[ \text{CH}_3-CH=CH-CH_3 \] ...
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Knowledge Check

  • Addition of Br_2 to cis-2-butene would give a product which is:

    A
    achiral
    B
    racemic
    C
    meso
    D
    optically active
  • Addition of BH_3 followed by H_2 O_2 to trans-2-butene would give a product which is:

    A
    achiral
    B
    racemic
    C
    meso
    D
    optically active
  • Addition of OsO_4 to cyclopentene would give a product which is:

    A
    achiral
    B
    racemic
    C
    meso
    D
    optically active
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