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Would you expect the second electron gai...

Would you expect the second electron gain enthalpy of O. as positive, more negative or less. negative than the first ? Justify your answer.

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Second electron gain enthalpy of O is positive because after the gain of one electron the oxygen atom acquires negative charge. Now when the second electron approaches the negatively charged oxygen atom, there is negative - negative repulsion. Hence, energy is to be supplied, so second electron gain enthalpy becomes positive.
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Knowledge Check

  • Fluorine has less negative electron gain enthalpy than chlorine due to:

    A
    Small size
    B
    High electro negativity
    C
    Absence of d-orbital
    D
    None of the above
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