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Why is nitric oxide paramagnetic in gase...

Why is nitric oxide paramagnetic in gaseous state but the solid obtained on cooling it is diamagnetic?

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If hydrogen atoms (in the ground state ) are passed through an homogeneous magnetic field, the beam is split into two parts. This interaction with the magnetic field shows that the atoms must have magnetic moment. However, the moment cannot be due to the orbital angular momentum since l=0. Hence one must assume existence of intrinsic angular momentum, which as the experiment shows, has only two permitted orientations. Spin of the electron produce angular momentum equal to S=sqrt(s(s+1))(h)/(2pi) where S=+(1)/(2) . Total spin of an atom = +(n)/(2) " or "-(n)/(2) where n is the number of unpaired electrons. The substance which contain species with unpaired electrons in their orbitals behave as paramagnetic substances. The paramagnetism is expressed in terms of magnetic moment. The magnetic moment of an atom mu_(s)sqrt(s(s+1))(eh)/(2pimc)=sqrt((n)/(2)((n)/(2)+1))(eh)/(2pimc)" "s=(n)/(2) impliesmu_(s)=sqrt(n(n+1)) B.M. 1. B.M. (Bohr magneton)= (eh)/(4pimc) If magnetic moment is zero the substance is diamagnetic. If an ion of _(25)Mn has a magnetic moment of 3.873 B.M. Then oxidation state of Mn in ion is :

If hydrogen atoms (in the ground state ) are passed through an homogeneous magnetic field, the beam is split into two parts. This interaction with the magnetic field shows that the atoms must have magnetic moment. However, the moment cannot be due to the orbital angular momentum since l=0. Hence one must assume existence of intrinsic angular momentum, which as the experiment shows, has only two permitted orientations. Spin of the electron produce angular momentum equal to S=sqrt(s(s+1))(h)/(2pi) where S=+(1)/(2) . Total spin of an atom = +(n)/(2) " or "-(n)/(2) where n is the number of unpaired electrons. The substance which contain species with unpaired electrons in their orbitals behave as paramagnetic substances. The paramagnetism is expressed in terms of magnetic moment. The magnetic moment of an atom mu_(s)sqrt(s(s+1))(eh)/(2pimc)=sqrt((n)/(2)((n)/(2)+1))(eh)/(2pimc)" "s=(n)/(2) impliesmu_(s)=sqrt(n(n+1)) B.M. 1. B.M. (Bohr magneton)= (eh)/(4pimc) If magnetic moment is zero the substance is diamagnetic. Which of the following ion has lowest magnetic moment?

MODERN PUBLICATION-p-BLOCK ELEMENTS-EXERCISE
  1. Why is nitric oxide paramagnetic in gaseous state but the solid obtain...

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  2. Which of the two NH3 and PH3 is more basic and why ?

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  3. How many significant figures are present in 4.01 × 10*2

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  4. Which of these is not a tree?

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  5. Which of the two NH3 and PH3 is soluble in water and why?

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  6. Arrange H(2)O, NH(3) " and "CH4 in the decreasing order of bond angle.

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  7. The cost of table salt (NaCl) is Rs 2 per Kg. Calculate the cost per m...

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  8. Give an example of compounds in which the oxidation state of nitrogen ...

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  9. Give an example of compounds in which the oxidation state of nitrogen ...

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  10. Give an example of compounds in which the oxidation state of nitrogen ...

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  11. What does the abbreviation T.N .T. stand for ?

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  12. What is laughing gas ? How is it prepared ?

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  13. Which plants mostly help in nitrogen fixing ?

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  14. Write the formula of the compound formed during ring test of nitrate ....

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  15. Name the oxide of nitrogen Which is blue solid ?

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  16. Name three oxoacids of nitrogen.

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  17. Which oxide of nitrogen is produced by heating lead nitrate ?

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  18. Give one example each of oxyacid of P having the oxidation state +4 .

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  19. What is the chemical formula of laughing gas ? How is it prepared ?

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  20. Among the hydrides of group 15, predict the hydride having most basic ...

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  21. Among the hydrides of group 15, predict the hydride having highest the...

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