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Propene (CH3 – CH = CH2) can be transfor...

Propene `(CH_3 – CH = CH_2) `can be transformed to compounds (a to j) listed in the left-hand column. Write letter designating the reagent, you believe will achieve desired transformation. In the case of a multi step sequence write the reagent in the order they are to be used.

Text Solution

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The correct Answer is:
a-D; b-A, C; c-B, E; d - A, C, F; e-B, E, F;f-F;g-G; h-I, K; i-B, E, I; J-D, L
(a) Halogenation (b) Oxymercuration-De-mercuration reaction (OMDM reaction) (c) Hydroboration-oxidation reaction (HBO reaction)
` (d) CH_3 CH =CH_2 overset(OMDM) to CH_3 - overset(O )overset(||)C-CH_3 underset("oxidising agent ")overset(HOBr)to CH_3 - CH_2 -CHO`
(f) Halohydrin formation (g) Markovnikoff addition (h) Oxidation reaction
`(i) CH_3-CH=CH_2 overset(HBO)to CH_3 -CH_2 -CH_2 -CH_2 -OH underset("Darzene process ")overset("SOCl_2)to CH_3 -CH_2 -CH_2 -Cl +SO_2 +HCl`
(j) Halogenation and elimination.
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Knowledge Check

  • Which reagent will you use for the following reaction? CH_(3)CH_(2)CH_(2)CH_(3)rarrCH_(3)CH_(2)CH_(2)CH_(2)Cl+CH_(3)CH_(2)CHClCH_(3)

    A
    `Cl_(2)//UV` light
    B
    `NaCl+H_(2)SO_(4)`
    C
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    D
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