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Oxidation state of Ni in Ni(CO)4 is...

Oxidation state of Ni in `Ni(CO)_4` is

A

`+2`

B

`0`

C

`+4`

D

`-8`

Text Solution

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The correct Answer is:
To determine the oxidation state of nickel (Ni) in the complex compound \( Ni(CO)_4 \), we can follow these steps: ### Step 1: Identify the components of the compound The compound \( Ni(CO)_4 \) consists of one nickel atom and four carbon monoxide (CO) ligands. ### Step 2: Assign oxidation states to the ligands In coordination compounds, the oxidation state of neutral ligands is typically zero. The carbon monoxide (CO) ligand is a neutral ligand, meaning it does not contribute any charge. Therefore, the oxidation state of each CO is 0. ### Step 3: Set up the equation for the oxidation state Let the oxidation state of nickel be represented by \( x \). Since there are four CO ligands, the total contribution from the ligands to the oxidation state is \( 4 \times 0 = 0 \). ### Step 4: Write the equation The overall charge of the complex \( Ni(CO)_4 \) is neutral (0). Therefore, we can write the equation: \[ x + 0 = 0 \] ### Step 5: Solve for the oxidation state of nickel From the equation, we have: \[ x = 0 \] ### Conclusion The oxidation state of nickel in \( Ni(CO)_4 \) is 0. ### Final Answer The oxidation state of Ni in \( Ni(CO)_4 \) is 0. ---

To determine the oxidation state of nickel (Ni) in the complex compound \( Ni(CO)_4 \), we can follow these steps: ### Step 1: Identify the components of the compound The compound \( Ni(CO)_4 \) consists of one nickel atom and four carbon monoxide (CO) ligands. ### Step 2: Assign oxidation states to the ligands In coordination compounds, the oxidation state of neutral ligands is typically zero. The carbon monoxide (CO) ligand is a neutral ligand, meaning it does not contribute any charge. Therefore, the oxidation state of each CO is 0. ...
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Knowledge Check

  • Oxidation number of Ni in Ni(CO)_(4) is-

    A
    0
    B
    4
    C
    8
    D
    2
  • The oxidation state of nickel in [Ni(CO)_(4)] is

    A
    4
    B
    0
    C
    2
    D
    3
  • Statement-1. Oxidation number of Ni in Ni(CO)_(4) , is zero Statement-2. Oxidation number of CO has been taken as zero.

    A
    Statement -1 is true, statement -2 is also true, statement -2 is the correct explanation of statement-1
    B
    Statement -1 is true, statement -2 is also true, statement-2 is not the corect explanation of statement-1
    C
    Statement -1 is true, statement -2 false
    D
    Statement -1 is false, statement -2 is true.
  • Similar Questions

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    What is the oxidation state of nickel in Ni(CO)_(4) ?

    Calculate the oxidation number of nickel in Ni(CO)_4 iron in Fe(CO)_5 and carbon in CH_2O .

    (A) Oxidation number of Ni in Ni(C0)_(4) is taken zero. (R ) The oxidation number of CO has been taken to be zero.

    EAN of Ni in [Ni(CO)_(4) is

    Assertion :- Oxidation number of Ni in [Ni(CO)_(4)] is zero. ltbr. Reason :- Nickel is bonded to neutral ligand, carbonyl.