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Formic acid is a reducing agent. Substan...

Formic acid is a reducing agent. Substantriate this statement with examples.

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Formic acid contains both an aldehyde as well as well as an acid group. Hence, like other aldehydes, formic acid can easily be oxidised and therefore acts as a strong reducing agents.

(i) Formic acid reduces Tollens reagent (ammonical silver nitrate solution) to metallic silver.
`HCOO^(-) + underset("(tollens reagent)")(2Ag^(+) + 3OH^(-)) to underset("silver mirror")(2Ag) + CO_3^(2-) + 2H_2O`
(ii) Formic acid reduces Fehlings solution. It reduces blue coloured cupric ions to red coloured cuprous ions.
`HCOO^(-) + underset(("fehlings solution"))(2Cu^(2+) + 5OH^(-)) to underset("red precipitate")(Cu_2O) + CO_3^(2-) + 3H_2O`
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Knowledge Check

  • Ca is a good reducing agent, because

    A
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    C
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