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Consider the following reaction: Cu(s)...

Consider the following reaction:
`Cu(s)+2Ag^(+)(aq) to 2Ag(s)+Cu^(2+)(aq)`
Depict the galvanic cell in which the given reaction takes place.

A

`Cu^(2+)(aq)|Cu(s)||Ag^(+)(aq)|Ag(s)`

B

`Cu(s)|Cu^(2+)(aq)||Ag^(+)(aq)|Ag(s)`

C

`Ag^(+)(aq)|Ag(s)||Cu^(2+)(aq)|Cu(s)`

D

`Ag(s)|Ag^(+)(aq)||Cu^(2+)(aq)|Cu(s)`

Text Solution

AI Generated Solution

The correct Answer is:
To depict the galvanic cell for the reaction \( \text{Cu}(s) + 2\text{Ag}^+(aq) \rightarrow 2\text{Ag}(s) + \text{Cu}^{2+}(aq) \), we need to follow these steps: ### Step 1: Identify Oxidation and Reduction - **Oxidation** is the loss of electrons. In this reaction, copper (Cu) is oxidized from its elemental state (0) to \( \text{Cu}^{2+} \) (2+), losing 2 electrons. - **Reduction** is the gain of electrons. Silver ions (\( \text{Ag}^+ \)) are reduced from a +1 oxidation state to solid silver (0), gaining 1 electron for each silver ion. ### Step 2: Write Half-Reactions - **Oxidation half-reaction**: \[ \text{Cu}(s) \rightarrow \text{Cu}^{2+}(aq) + 2e^- \] - **Reduction half-reaction**: \[ 2\text{Ag}^+(aq) + 2e^- \rightarrow 2\text{Ag}(s) \] ### Step 3: Construct the Galvanic Cell 1. **Anode (Oxidation Site)**: This is where oxidation occurs. Place copper (Cu) at the anode. - **Anode Reaction**: \( \text{Cu}(s) \rightarrow \text{Cu}^{2+}(aq) + 2e^- \) 2. **Cathode (Reduction Site)**: This is where reduction occurs. Place silver ions (\( \text{Ag}^+ \)) at the cathode. - **Cathode Reaction**: \( 2\text{Ag}^+(aq) + 2e^- \rightarrow 2\text{Ag}(s) \) 3. **Salt Bridge**: Connect the two half-cells with a salt bridge to maintain electrical neutrality. ### Step 4: Label the Components - **Left Side (Anode)**: - Copper electrode (Cu) - Copper ions in solution (\( \text{Cu}^{2+} \)) - **Right Side (Cathode)**: - Silver ions in solution (\( \text{Ag}^+ \)) - Silver electrode (Ag) ### Final Representation of the Galvanic Cell: The galvanic cell can be represented as: \[ \text{Cu}(s) | \text{Cu}^{2+}(aq) || \text{Ag}^+(aq) | \text{Ag}(s) \]

To depict the galvanic cell for the reaction \( \text{Cu}(s) + 2\text{Ag}^+(aq) \rightarrow 2\text{Ag}(s) + \text{Cu}^{2+}(aq) \), we need to follow these steps: ### Step 1: Identify Oxidation and Reduction - **Oxidation** is the loss of electrons. In this reaction, copper (Cu) is oxidized from its elemental state (0) to \( \text{Cu}^{2+} \) (2+), losing 2 electrons. - **Reduction** is the gain of electrons. Silver ions (\( \text{Ag}^+ \)) are reduced from a +1 oxidation state to solid silver (0), gaining 1 electron for each silver ion. ### Step 2: Write Half-Reactions - **Oxidation half-reaction**: ...
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Consider the following reaction : Cu(s)+2Ag^(+)(aq)to 2Ag(s) +Cu^(2+)(aq) (i) Depict the galvanic cell in which the given reaction takes place. (ii) Give the direction of flow of current. (iii) Write the half-cell reactions taking place at cathode and anode.

Consider the following reaction : Cu (s) + 2Ag^+ (aq) to 2Ag (s) + Cu^(2+) (aq) (i) Depict the galvanic cell in which the given reaction takes palce. (ii) Give the direction of flow of current (iii) Write the half-cell reactions taking place at the cathode and anode.

Knowledge Check

  • In the reaction , Cu(s)+2Ag^(+)(aq)rarrCu^(2+)(aq)+2Ag(s) , the reduction half cell reaction is

    A
    `Cu+2e^(-)rarrCu^(2+)`
    B
    `Cu-2e^(-)rarrCu^(2+)`
    C
    `Ag^(+)+e^(-)rarrAg`
    D
    `Ag^(-)e^(-)rarrAg^(+)`
  • Consider the following cell reaction Cu(s)+2Ag^(+)(aq) rarr Cu^(2+) (aq) +2Ag(s) E_("cell")^(@)=0.46 V By boubling the concentration of Cu^(2+) , E_("cell") is

    A
    doubled
    B
    halved
    C
    increases nut less than double
    D
    decreases by a small fraction
  • Following reaction is an example of Ag^(2+) (aq) + Ag (s) hArr 2Ag^(+) (aq)

    A
    reduction
    B
    oxidation
    C
    comproportionation
    D
    disproportionation
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