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Assertion (A): While the extraction of c...

Assertion (A): While the extraction of copper, one of the steps involved is
`Cu_(2)S+2Cu_(2)O to 6Cu+SO_(2)`
Reason (R): In this reaction `Cu_(2)S` is the reducing agent whereas `Cu_(2)O` is the oxidising agent.

A

Both A and R are true and R is the correct explanation of A.

B

Both A and R are true but R is NOT the correct explanation of A

C

A is true but R is false

D

A is false and R is true.

Text Solution

AI Generated Solution

The correct Answer is:
### Step-by-Step Solution: 1. **Understanding the Reaction**: The given reaction is: \[ \text{Cu}_2\text{S} + 2\text{Cu}_2\text{O} \rightarrow 6\text{Cu} + \text{SO}_2 \] This reaction is part of the extraction process of copper. 2. **Identifying Oxidation States**: - In \(\text{Cu}_2\text{S}\), sulfur (S) has an oxidation state of -2. Therefore, the oxidation state of copper (Cu) can be calculated as follows: \[ 2x - 2 = 0 \implies x = +1 \] Thus, in \(\text{Cu}_2\text{S}\), copper is in the +1 oxidation state. - In \(\text{Cu}_2\text{O}\), oxygen (O) has an oxidation state of -2. Therefore, the oxidation state of copper is: \[ 2x - 2 = 0 \implies x = +1 \] Thus, in \(\text{Cu}_2\text{O}\), copper is also in the +1 oxidation state. 3. **Determining Changes in Oxidation States**: - In the products, elemental copper (Cu) has an oxidation state of 0. - The sulfur in \(\text{SO}_2\) has an oxidation state of +4. 4. **Identifying Reducing and Oxidizing Agents**: - A reducing agent is a substance that donates electrons and is oxidized in the process. Here, \(\text{Cu}_2\text{S}\) is oxidized to \(\text{Cu}\), indicating it is acting as a reducing agent. - An oxidizing agent is a substance that accepts electrons and is reduced in the process. Here, \(\text{Cu}_2\text{O}\) is also reduced to \(\text{Cu}\), indicating it is acting as an oxidizing agent. 5. **Evaluating the Assertion and Reason**: - **Assertion (A)**: The statement about the reaction being part of copper extraction is true. - **Reason (R)**: The statement that \(\text{Cu}_2\text{S}\) is a reducing agent and \(\text{Cu}_2\text{O}\) is an oxidizing agent is also true. 6. **Conclusion**: Since both the assertion and the reason are true, the correct answer is that both statements are true. ### Final Answer: - Assertion (A) is true. - Reason (R) is true. - Therefore, both A and R are correct.

### Step-by-Step Solution: 1. **Understanding the Reaction**: The given reaction is: \[ \text{Cu}_2\text{S} + 2\text{Cu}_2\text{O} \rightarrow 6\text{Cu} + \text{SO}_2 \] This reaction is part of the extraction process of copper. ...
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The following reactions take place during the extraction of copper from copper ore. (i) 2Cu_(2)S(l) + 3O_(2)(g) rarr 2Cu_(2)O(l) + 2SO_(2)(g) (ii) 2Cu_(2)O(l) + Cu_(2)S(l) rarr 6 Cu(l) + SO_(2)(g) Identify the oxidizing and reducing agents.

Knowledge Check

  • Colour of Cu_(2)O is due to

    A
    d-d transition
    B
    charge transfer
    C
    f-f transition
    D
    geometry of `Cu_(2)O`
  • Colour of the Cu_(2)O is due to

    A
    d-d transition
    B
    p-p transition
    C
    charge transfer
    D
    f-f transition
  • From the graph, which is the best reducing agent to reduce Cu_(2)O at high temperature

    A
    Coke
    B
    CO
    C
    `CO_(2)`
    D
    1&2
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